Go toArchive
Browse byFacets
Bookbag ( 0 )
'Tincluster' in keywords
Results  1 Item
Sorted by   
Section
Publication Year
1999 (1)
1Author    Nils Wiberg, Hans-Wolfram Lemer, Susanne Wagner, Heinrich Nöth+, Thomas Seifert+Requires cookie*
 Title    On an Octastannanediide R*6Sn8[Na(THF)2]2 and the Possible Existence of an Octastannane R*6Sn8 [ 1 ]  
 Abstract    The black, air and moisture sensitive octastannanediide R*6Sn8[Na(THF)2]2 (4) (R* = Si/Bu3) is prepared by reaction of Sn[N(SiM e3)2]2 with R*Na in rBuOMe at -78°C . Red brown octa­ stannane R*6Sn8 (5) is formed by thermolysis of the tristannacyclopropene R*4Sn3 in benzene at 100 °C. According to the result of the X-ray structural analysis, 4 contains a Sn8 cubane with six Sn atoms each connected with R* and two at the end o f a space diagonal connected with Na(THF)2. A preliminary X-ray structure analysis shows 5 to adopt the same Sn8 cubane structure as 4 with two bare Sn atoms at the end of a space diagonal. 
  Reference    Z. Naturforsch. 54b, 877—880 (1999); eingegangen am 1. April 1999 
  Published    1999 
  Keywords    Silicon, Tin, Sodium, Tincluster, X-Ray Data 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-0877.pdf 
 Identifier    ZNB-1999-54b-0877 
 Volume    54