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'Thiotrithiazyl chloroselenates' in keywords
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1989 (1)
1Author    HansG. Eorg Stammler, Johannes WeissRequires cookie*
 Title    Synthese  
 Abstract    und Kristallstruktur von (S4N3)2Se2Cl10, (S4N3)2Se2CI6 und [(S4N3)SeCl5]n Synthesis and Crystal Structure of (S4N3)2Se2C l10, (S4N3)2Se2Cl6, and [(S4N 3)SeCl5]" (S4N 3)2S e2C l10, (S4N 3)2Se2Clft and [(S4N 3)SeC l5]" are formed by the reaction o f S4N 4, Se2Cl2, and SO C l2. The structures o f the three com pounds where determ ined by X-ray diffraction. The yellow crystals o f (S4N 3)2Se2C l10 are monoclinic, space group P 2,/a, a = 817.5(2) pm , b = 1790.4(5) pm, c = 843.1(6) pm, ß = 104.31(4)°, Z = 2. The Se2C l102~ anion consists o f 2 Cl-bridged distorted octahedra. (S4N 3)2Se2Cl6 forms red m onoclinic crystals, space group P2,/c, a = 1036.5(3) pm , b = 1376.5(5) pm , c = 1400.4(4) pm ,/3 = 100.65(2)°, Z = 4. In the Se2Cl62" anion the Se atoms have a square planar environm ent. The yellow crystals o f (S4N 3)SeC l5 are orthorhom bic, space group P 2 12 12 1, a = 734.2(3) pm , b — 989.4(4) pm , c = 1627.4(6) pm , Z = 4. In the SeC l5_ anion the Se atom has an octahedral environm ent o f chlorine atom s, thus forming a polym eric structure. 
  Reference    Z. Naturforsch. 44b, 1483 (1989); eingegangen am 5. Mai 1989 
  Published    1989 
  Keywords    Thiotrithiazyl-chloroselenates, Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-1483.pdf 
 Identifier    ZNB-1989-44b-1483 
 Volume    44