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'Thioindates' in keywords Facet   section ZfN Section B  [X]
Facet   Publication Year 1980  [X]
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1Author    Hans-Jörg DeiserothRequires cookie*
 Title    Rb6In2S6 und Rb4In2S5, zwei neue Thioindate mit isolierten und verknüpften [In2S6] fi ~ Anionen Rbßl^Se and Rb4ln2Ss, Two NEW Thioindates with Isolated and Connected [I^Se] 6-Anions Respectively  
 Abstract    The hitherto unknown title compounds were prepared by a disproportionation reaction starting from elementary rubidium and indium monosulfide. Rb4ln2Ss crystallizes in the triclinic system (P 1) with the lattice constants a = 931.7(2); d> = 1097.6(3);c = 761.2(2)pm; a = 111.32°(2); ß = 94.70°(2); y = 103.70°(2) (Z = 2) and Rb6In2S6 in the monoclinic system (C2/m) with the lattice constants a = 895.3(2); b = 1356.9(2); c = 791.8(2) pm; ß = 101.53°(2) (Z = 2). The quasi molecular [I^Se] 6-group which is isoelectronic with the gas phase molecule I^Clg consists of two edge sharing InS4 tetrahedra and is the basic unit of Rb4ln2Sö as well as of RbgL^Se. The formation process, structural relationships between the two compounds and their possible role in the phase diagram of the components Rb2S and L12S3 are discussed. 
  Reference    Z. Naturforsch. 35b, 953—958 (1980); eingegangen am 18. März 1980 
  Published    1980 
  Keywords    Crystal Structures, Indium Compounds, Rubidium Compounds, Ternary Sulfides, Thioindates 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0953.pdf 
 Identifier    ZNB-1980-35b-0953 
 Volume    35