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'Thioether Thiolate Amine Ligands' in keywords
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1994 (1)
1Author    D. Ieter Sellmann, Thomas Hofmann, Falk KnochRequires cookie*
 Title    Ni(II)-und Ni(III)-Komplexe mit dem fünfzähnigen Thioether- Thiolat-Amin-Liganden 'NMeS4'2_ ('NMeS4'2_ = Dianion von 2,2'-Bis(2-mercaptophenylthio)diethylmethylamin) Transition Metal Complexes with Sulfur Ligands, CV* Ni(II) and Ni(III) Complexes with the Pentadentate Thioether- Thiolate-Amine-Ligand 'N MeS4'2_ ('N MeS4'2-= Dianion of 2.2'-Bis(2-m ercaptophenylthio)diethylmethylamine)  
 Abstract    Paramagnetic [N i('N MeS4')]2 1 ('N MeS4'2_ = 2.2'-Bis(2-m ercaptophenylthio)diethylm ethyl-a m in e(2 -)) was synthesized from N i(ac)2 and N a2-'N MeS4' and characterized by X-ray structure analysis. In solid state, 1 contains two pseudo-octahedral [N i('N MeS4')] fragments bridged via thiolate donors. In contrast to the parent com plex [N i('N HS4')]2, the thiolate and thioether donors coordinate cis to the Ni center forming m eso [N i('N MeS4')] fragments of Cs symmetry. 1 readily dissociates in solution to give mononuclear [N i('N MeS4')]. Reaction of [N i('N MeS4')]2 1 with PM e3 yielded [N i(PM e3)('N MeS4')] 2, oxidation by io­ dine gave the Ni(III) complex [N i(I)('N MeS4')] 3. Ubergangsmetallkomplexe mit Schwefel-Liganden, CY* 
  Reference    Z. Naturforsch. 49b, 821 (1994); eingegangen am 15. Februar 1994 
  Published    1994 
  Keywords    Nickel Complexes, Thioether-Thiolate-Amine-Ligands, X-Ray 
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 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-0821.pdf 
 Identifier    ZNB-1994-49b-0821 
 Volume    49