| | 1 | Author
| A. G. Galinos, J. K. Kouinis, P. V. Ioannou, ThF. Zafiropoulos, S. P. Perlepes | Requires cookie* | | | Title
| Compounds of Complex Halo and Pseudohalo Acids of the Group II B Metals, Part I Etherate, Pyridine and Aniline Compounds of Zn(II)  | | | | Abstract
| The preparation of sixteen new etherate, pyridine and aniline compounds of complex halo and pseudohalo acids of Zn(II) is reported. The study of some physical and chemical properties as well as the UV and IR spectra of these compounds are discussed. Tetrahedral structures are proposed for all compounds in the solid state. | | | |
Reference
| Z. Naturforsch. 34b, 1101—1106 (1979); received May 11 1979 | | | |
Published
| 1979 | | | |
Keywords
| Ether, Pyridine, Aniline, Thiocyanate, Zinc | | | |
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| default:Reihe_B/34/ZNB-1979-34b-1101.pdf | | | | Identifier
| ZNB-1979-34b-1101 | | | | Volume
| 34 | |
| 2 | Author
| Wim Vreugdenhil, MarcelF J Schoondergang, JaapG. Haasnoot, Jan Reedijk | Requires cookie* | | | Title
| Magnetic and Spectroscopic Properties of Metal(II) Thiocyanate Compounds with 3,4-Dialkyl Substituted 1,2,4-TriazoIes | | | | Abstract
| Syntheses, spectroscopic and magnetic properties are described of a series of metal(II) thio-cyanate compounds with the asymmetric ligands 3-methyl-4-ethyl-l,2,4-triazole and 3-methyl-4-;-butyl-l,2,4-triazole. A dinuclear structure is proposed for the manganese, cobalt and nickel compounds based on the magnetic behaviour as well as on spectroscopic and analytical data. These compounds show antiferromagnetic interaction in the temperature range 4—80 K. The zinc compounds appear to be mononuclear, whereas a chain-like structure is proposed for the cad-mium compounds. | | | |
Reference
| Z. Naturforsch. 42b, 791—795 (1987); received January 19 1987 | | | |
Published
| 1987 | | | |
Keywords
| Asymmetric 1, 2, 4-Triazoles, Magnetic Exchange, Binuclear Compounds, Thiocyanate | | | |
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| default:Reihe_B/42/ZNB-1987-42b-0791.pdf | | | | Identifier
| ZNB-1987-42b-0791 | | | | Volume
| 42 | |
| 3 | Author
| JuliaA. Manskaya, VolodimirN. Kokozay, KonstantinV. Domasevitch | Requires cookie* | | | Title
| Crystal Structure of an Ammonium Dithiocyanatocuprate(I) Complex with 18-Crown-6, [NH4(18-Crown-6){Cu(NCS)2}] Obtained from Zero Valent Metal | | | | Abstract
| The new macrocyclic dithiocyanatocuprate(I) complex [NH4(18-crown-6){Cu(NCS)2}] has been prepared using a direct method of interaction and characterized by X-ray crystallogra phy (orthorhombic, space group Cmc2i, with a = 12.453(2), b = 21.650(4), c = 8.151(2) A, V = 2197.6(8) Ä3, Z = 4 , 1 (F) = 0.054; wR2(F2) = 0.141 for 972 unique reflections with I > 2<r(I) and /?1(F) = 0.082; w/?2(F2) = 0.210 for all 1098 unique reflections). The lattice comprises complex cations [NH4(18-crown-6)]+ and infinite polymeric anions [Cu(NCS)2]-of a one-dimensional zig-zag structure. The copper atoms adopt three-fold coordination [CuN^S] (Cu-N 1,89(1), 1,90(1) A; Cu-S 2.278(4) A). | | | |
Reference
| Z. Naturforsch. 52b, 1311—1314 (1997); received | | | |
Published
| 1997 | | | |
Keywords
| 18-Crown-6, Copper(I), Thiocyanate, Synthesis, X-Ray | | | |
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| default:Reihe_B/52/ZNB-1997-52b-1311.pdf | | | | Identifier
| ZNB-1997-52b-1311 | | | | Volume
| 52 | |
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