| | 1 | Author
| Helmut Burdorf, Christoph Eischenbroich | Requires cookie* | | | Title
| Metall-rr-Komplexe yon Benzolderivaten, XIII [1] Bis(methylthio-/-beiizol)chrom(0) Darstellung und Einsatz als zweizähniger Chelatligand  | | | | Abstract
| The thioanisole-7r-complexes (methylthio-^-benzene)-(^-benzene)-chromium (2) and bis(methylthio-r/-benzene)chromium (3) have been prepared via lithiation of bis(rj-benzene)-chromium and consecutive reaction with dimethyldisulfide. *H NMR and 13 C NMR spectra of 2 and 3 as well as ESR-spectra of the corresponding radical cations 2t and 3t were recorded and analyzed. In contrast to C(»?.arene)-Si and C(r/-arene)-P bonds, C(1/.arene)-S bonds are stable to solvolysis. With (norbornadiene)tetracarbonylmolybdenum, 3 readily forms [bis(methylthio-?j-benzene)chromium]tetracarbonylmolybdenum (6) wherein 3 functions as a chelating ligand. *H and 13 C NMR evidence suggests, that at room temperature 6 undergoes rapid conformational interconversions. | | | |
Reference
| (Z. Naturforsch. 36b, 94—101 [1981]; eingegangen am 9. September 1980) | | | |
Published
| 1981 | | | |
Keywords
| Thioanisole Sandwich Complexes, X H NMR Spectra, 13 C NMR Spectra, ESR Spectra, Coordination Chemistry | | | |
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| default:Reihe_B/36/ZNB-1981-36b-0094.pdf | | | | Identifier
| ZNB-1981-36b-0094 | | | | Volume
| 36 | |
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