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1988 (1)
1Author    Christiane Löwe, Gottfried Huttner, Laszlo Zsolnai, Heinz BerkeRequires cookie*
 Title    Acetalisierte Formylmangan-Komplexe Acetals of Formyl Manganese Complexes  
 Abstract    Acetal complexes of the type (OC) 5 MnCH(XR) 2 , RX = PhO (la), (RX) 2 = 1,2-dioxybenzene (lb), (RX), = S-(CH,),-S (2) and (OC),[P(OCH,),],MnCHS-(CH,),-S (5) were synthesized. Glyoxyloyl acetal derivatives (0C) 5 MnC(0)CH(XR) 2 . RX = PhO (3a), (RX) 2 = 1,2-dioxyben-zene (3b), (RX) 2 = S-(CH 2),-S (4) were obtained by the action of NaMn(CO) 5 upon the corresponding acid chlorides or anhydrides, la can be transformed to 3a by CO insertion, la has been characterized by an X-ray structure determination. 
  Reference    (Z. Naturforsch. 43b, 25—30 [1988]; eingegangen am 31. Juli/9. Oktober 1987) 
  Published    1988 
  Keywords    Acetals, Thioacetals, Formyl and Glyoxyloyl Manganese Carbonyl Complexes X-Ray 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0025.pdf 
 Identifier    ZNB-1988-43b-0025 
 Volume    43