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'Thermal Decomposition' in keywords Facet   Publication Year 1981  [X]
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1981[X]
1Author    Edgar Niecke, Anke Nickloweit-Lüke, Reinhold Rüger, Bernt Krebs, Helmut GreweRequires cookie*
 Title    .2A 3 .3A 3 -Azadiphosphiridine -Synthese, Kristallstruktur und Eigenschaften 1,2 A 3 ,3 x 3 -Azadiphosphiridines -Synthesis, Crystal Structure and Proj)erties  
 Abstract    1,2 A 3 ,3 A 3 -Azadiphosphiridines are avaüable by elimination of hydrogenhalide from ß-and y-functional molecular frameworks and by 1 + 2 cycloaddition of phosphinidenes towards aminoiminophosphanes. In contrast to other three-membered phosphorus com-pounds, azadiphosphiridines decompose by 2 +1 cycloreversion to aminoiminophosphanes and phosphinidenes. The molecular structure of an azadiphosphiridine demonstrates the trans arrangement of the exocyclic ligands and the planarity of the endocyclic nitrogen. 
  Reference    Z. Naturforsch. 36b, 1566—1574 (1981); eingegangen am 13. Juli 1981 
  Published    1981 
  Keywords    Azadiphosphiridines, Cyclisation, Thermal Decomposition, NMR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-1566.pdf 
 Identifier    ZNB-1981-36b-1566 
 Volume    36