| 1 | Author | Hermann Rau, Otto Schuster | Requires cookie* |
| Title | Eine theoretische Begründung empirischer Sektorenregeln der optischen Aktivität Theoretical Verification of Empirical Sector Rules of Optical Activity  | ||
| Abstract | A simple procedure for derivation of octant rules for optically active molecules con-taining a chromophoric group is developed within the framework of Kuhn's classical model of coupled oscillators. The important feature in this derivation is the clue that the locus of the center of gravity of the atoms not belonging to the chromophoric group and the direction of maximum polarizability of this ensemble of atoms are not independent. The octant rule for carbonyl compounds arrived at by this procedure is in agreement with the empirical one. A newly derived rule for cis-azo compounds is verified by empirical data. | ||
| Reference | Z. Naturforsch. 34b, 1519—1524 (1979); eingegangen am 24. Juli 1979 | ||
| Published | 1979 | ||
| Keywords | Optical Activity, Coupled Oscillator Model, Theoretical Sector Rules, cis-azo Compounds | ||
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