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1979 (1)
1Author    Hermann Rau, Otto SchusterRequires cookie*
 Title    Eine theoretische Begründung empirischer Sektorenregeln der optischen Aktivität Theoretical Verification of Empirical Sector Rules of Optical Activity  
 Abstract    A simple procedure for derivation of octant rules for optically active molecules con-taining a chromophoric group is developed within the framework of Kuhn's classical model of coupled oscillators. The important feature in this derivation is the clue that the locus of the center of gravity of the atoms not belonging to the chromophoric group and the direction of maximum polarizability of this ensemble of atoms are not independent. The octant rule for carbonyl compounds arrived at by this procedure is in agreement with the empirical one. A newly derived rule for cis-azo compounds is verified by empirical data. 
  Reference    Z. Naturforsch. 34b, 1519—1524 (1979); eingegangen am 24. Juli 1979 
  Published    1979 
  Keywords    Optical Activity, Coupled Oscillator Model, Theoretical Sector Rules, cis-azo Compounds 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-1519.pdf 
 Identifier    ZNB-1979-34b-1519 
 Volume    34