| | 1 | Author
| B. Mertens, Hk Müller-Buschbaum | Requires cookie* | | | Title
| Synthese und Röntgen-Strukturuntersuchung von  | | | | Abstract
| Rb4Cd(V0)(V2 0 7)2Cl und Tl4C d(V0)(V20 7)2Cl Synthesis and X-Ray Structure Analysis o f Rb4C d (V 0)(V 20 7)2Cl and Tl4C d(V 0)(V 20 7)2Cl Single crystals of (I) Rb4Cd(V0)(V20 7)2Cl and (II) Tl4C d(V 0)(V 20 7)2Cl have been prepared by flux techniques. The compounds were examined by X-ray analysis. They crystallize with tetragonal symmetry, space group C{-P4 with (I): a = 9 .142(1); c = 5.525(1), (II): a = 9.150(1), c = 5.405(1) A, Z = 4. Both compound belong to the K4CuV50 | 5Cl-Type. V (l) forms V20 7 double tetrahedra, connected by square V (2)0 5 pyramids and C d 0 4Cl2 octahedra. The short V (2)-0 distance indicates a vanadyl group. | | | |
Reference
| Z. Naturforsch. 52b, 453—456 (1997); eingegangen am 27. Januar 1997 | | | |
Published
| 1997 | | | |
Keywords
| Rubidium, Thallium, Vanadium Oxide-Chloride, Crystal Structure | | | |
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| default:Reihe_B/52/ZNB-1997-52b-0453.pdf | | | | Identifier
| ZNB-1997-52b-0453 | | | | Volume
| 52 | |
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