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1999 (1)
1980 (2)
1Author    Klaus Brodersen, Klaus-Peter Jensen, Gerhard ThieleRequires cookie*
 Title    Die Kristallstruktur des Xl10Hg3Cl16 The Crystal Structure of Tli0Hg3Cli6  
 Abstract    The structure of TlioHggClie (tetragonal; space group I4/m; a — 849,0(2) pm, c = 2372,9(6) pm) was determined by X-ray structure analysis. This compound consists of HgCLi tetrahedra and linear Cl-Hg-Cl units, which are completed by four additional chlorides to distorted (2 + 4) HgCle octahedra. A close relationship to the Tl4HgXe structure (X = Br, I) is discussed. 
  Reference    Z. Naturforsch. 35b, 259—264 (1980); eingegangen am 14. Dezember 1979 
  Published    1980 
  Keywords    Crystal Structure, Chloromercurate, Thallium(I) 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0259.pdf 
 Identifier    ZNB-1980-35b-0259 
 Volume    35 
2Author    VictorA. Trusha, KonstantinV. Domasevitcha, VladimirM. Amirkhanov2, Joachim SielerbRequires cookie*
 Title    Structure of Tl(18-cr0wn-6){Cl3C C (0)N P (0)(0C H 3)2}: Coordination of the Ionic Multidentate Weakens the Interaction of the Metal Atom with the Crown Ether  
 Abstract    The thallium(I) dimethyl-N-trichloroacetylamidophosphate complex with a 18-crown-6 of the composition Tl(18-crown-6){L} (L = {Cl3CC(0)NP(0)(0 CH3)2}_) has been prepared and characterized by means of IR spectroscopy and X-ray diffraction (orthorhombic, space group P2,2,2, with a = 8.660(1), b = 11.557(2), c =26.296(3) A, Z = 4, V = 2631.8(6) Ä3; R\ = 0.0285 and wR2 = 0.0558 for 4314 unique reflections). It was shown that (L~) is coordinatedoto the central atom in a bidentate manner via oxygen atoms of phosphoryl [Tl-O(l) 2.678(4) A] and carbonyl groups [Tl-0(2) 3.012(6) A], The Tl(18-crown-6)+ moiety adopts a typical "sunrise" coordination with the metal atom laying 1.134(2) A above the mean plane of the oxygen atoms of the macrocycle. This deviation is the highest value of the structurally examined Tl(18-crown-6)+ complexes. The Tl-O (etheric) separations are in the range 2.913(4) -3.198(5) A (av. 3.030(6) A). 
  Reference    Z. Naturforsch. 54b, 451—455 (1999); received September 29 1998 
  Published    1999 
  Keywords    Thallium(I), Crown Ethers, Carbacylamidophosphates, X-Ray Data 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-0451.pdf 
 Identifier    ZNB-1999-54b-0451 
 Volume    54 
3Author    Reinhild Böhme, Jörg Rath, Bernd Grunwald, Gerhard ThieleRequires cookie*
 Title    Über zwei Modifikationen von "T12C13"-valenzgemischten Thallium(I)-hexahalogenothallaten(III) Tlg [T1C16] On Two Modifications of "Tl2Cl3"-Mixed Valence Thallium(I)-hexahalogenothallates(III)  
 Abstract    The mixed valence thallium chloride "TI2CI3" is polymorphous. Raman spectra and comparable lattice translations suggest similar structures of both modifications. 
  Reference    Z. Naturforsch. 35b, 1366—1372 (1980); eingegangen am 8. August 1980 
  Published    1980 
  Keywords    Chlorothallate(III), Thallium(I), Valence Mixed Compound, Crystal Structure 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1366.pdf 
 Identifier    ZNB-1980-35b-1366 
 Volume    35