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'Tetrazolyl Enols' in keywords
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1997 (1)
1996 (1)
1Author    Eva-M Struckb, Karl Aria Peters0, H. Petersc, Georg Ans, Von SchneringcRequires cookie*
 Title    Verknüpfung koordinativ ungesättigter Kupfer(II)-Monomere via Cyano-versus Tetrazolyl-Donor [1]  
 Abstract    Reaction of a methanolic copper(II) acetate solution with tetrazolyl enol derivatives 2a (HL2) or 2b (HL3) leads to the formation of the corresponding 2D-coordination polymers 4 (^ [CuL^]) and 5 (^ [CuL2]), respectively. Single-crystal X-ray diffraction of the supramolecular species 4 and 5 established unequivocally the structures of the regioisomeric coordination polymers. On the contrary, reactions of 2c (HL4) with methanolic copper(II) acetate solution and 2b (HL3) with methanolic zinc(II) acetate solution yield mononuclear chelate complexes 11 ([CuL2]) and 12 ([ZnL2(MeOH)2]). The structures of 11 and 12 have been established by X-ray structure analysis. 
  Reference    Z. Naturforsch. 51b, 399—408 (1996); eingegangen am 14. August 1995 
  Published    1996 
  Keywords    Tetrazolyl Enols, Coordination Polymers 2D Copper Complexes, Spontaneous Self-Assembly, X-Ray 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0399.pdf 
 Identifier    ZNB-1996-51b-0399 
 Volume    51 
2Author    RolfW. Saalfrank3, Roland Harbig3, Oliver Struck, Frank Hampel3, Eva Maria Petersc, Karl Petersc, HansG. Eorg, Von SchneringcRequires cookie*
 Title    Eindimensionale Kupfer(II)-Koordinationspolymere: Kristall-Engineering durch variable Verknüpfungsmuster [1] One Dimensional Copper(II) Coordination Polymers: Crystal Engineering through Variable Types of Linkage [1]  
 Abstract    of a methanolic copper(II) acetate solution with tetrazolyl enol derivatives 2a or 2b leads to the formation of the corresponding lD-coordination polymer ^[CuL2] 3a and pseudo lD-coordination polymer [CuL2]2 3b, respectively. On the contrary, reaction of 2c with methanolic copper(II) acetate solution yields OH-bridged lD-coordination polymer ^[CuL2(MeOH)2l 3c. Single-crystal X-ray diffraction of the supramolecular species 3 established unequivocally the structures of the stairlike coordination compounds. Reaction of a methanolic copper(II) acetate solution with amidotetrazole derivative 6 leads to the formation of the lD-coordination polymer ^,[CuL2] 7. The structure of 7 has been established by X-ray structure analysis. 
  Reference    (Z. Naturforsch. 52b, 125—134 [1997]; eingegangen am 6. August 1996) 
  Published    1997 
  Keywords    Tetrazolyl Enols, Coordination Polymers ID, Copper Complexes, Self-Assembly, Crystal Engineering Reaction 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0125.pdf 
 Identifier    ZNB-1997-52b-0125 
 Volume    52