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'Tetrathiophosphorylhexaimid' in keywords
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1981 (1)
1Author    Heinrich Nöth, Volker ThornRequires cookie*
 Title    Ligandenstabilisierung durch Komplexbildung: P.P\P''-Triaminocyclotriphosphazan und adamantananaloges Tetraphosphorhexaimid Stabilisation of Ligands by Complex Formation: P,P',P"-Triaminocyclotriphosphazane and an Adamantane-Analogous Tetraphosphorus Hexaimide  
 Abstract    The thermal decomposition of (CO)5MP(NH2)3 (M = Cr, Mo, W) has been studied. No definite products were obtained for M = W but the molybdenum complex yielded [(CO)öMoP]4(NH)6. The same type of complex results with M = Cr, in addition to [(CO)5CrP(NH)NH2]3. The pentacarbonylchromium groups may be removed from the adamantane type [(CO)5CrP]4(NH)e with sulfur. The new compound S4P4(NH)6 results in this reaction. This compound is also a by-product in the thermal decomposition of SP(NH2)3. Attempts to prepare P4(NH)6 by desulfurisation from S4P4(NH)6 or from the chromium complex failed. 
  Reference    Z. Naturforsch. 36b, 1424—1431 (1981); eingegangen am 7. Mai 1981 
  Published    1981 
  Keywords    P, P', P"-Triaminocyclotriphosphazan, Tetraphosphorhexaimid, Tetrathiophosphorylhexaimid 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-1424.pdf 
 Identifier    ZNB-1981-36b-1424 
 Volume    36