| | 1 | Author
| Heinrich Nöth, Volker Thorn | Requires cookie* | | | Title
| Ligandenstabilisierung durch Komplexbildung: P.P\P''-Triaminocyclotriphosphazan und adamantananaloges Tetraphosphorhexaimid Stabilisation of Ligands by Complex Formation: P,P',P"-Triaminocyclotriphosphazane and an Adamantane-Analogous Tetraphosphorus Hexaimide  | | | | Abstract
| The thermal decomposition of (CO)5MP(NH2)3 (M = Cr, Mo, W) has been studied. No definite products were obtained for M = W but the molybdenum complex yielded [(CO)öMoP]4(NH)6. The same type of complex results with M = Cr, in addition to [(CO)5CrP(NH)NH2]3. The pentacarbonylchromium groups may be removed from the adamantane type [(CO)5CrP]4(NH)e with sulfur. The new compound S4P4(NH)6 results in this reaction. This compound is also a by-product in the thermal decomposition of SP(NH2)3. Attempts to prepare P4(NH)6 by desulfurisation from S4P4(NH)6 or from the chromium complex failed. | | | |
Reference
| Z. Naturforsch. 36b, 1424—1431 (1981); eingegangen am 7. Mai 1981 | | | |
Published
| 1981 | | | |
Keywords
| P, P', P"-Triaminocyclotriphosphazan, Tetraphosphorhexaimid, Tetrathiophosphorylhexaimid | | | |
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| default:Reihe_B/36/ZNB-1981-36b-1424.pdf | | | | Identifier
| ZNB-1981-36b-1424 | | | | Volume
| 36 | |
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