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'Tetrathiometallates' in keywords Facet   section ZfN Section B  [X]
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2001 (1)
1Author    Matthias Wanner3, Ingo Hartenbach3, Jan Fiedler, Thomas Schleid3, Wolfgang Kaim3Requires cookie*
 Title    Zwei  
 Abstract    -und dreikemige Organometallkomplexe (ReS4)[MCl(C5Me5)], M = Rh, Ir, und (/x-WS4)[IrCl(C5Me5)]2 Dinuclear and Trinuclear Organometallic Complexes (ReS4)[MCl(C5Me5)], M = Rh, Ir, and (Ai-WS4)[IrCl(C5Me5)]2 The reactions of tetrathiorhenate(VII) or tetrathiotungstate(VI) with [MCl2 (C5 Me5)]2, M = Rh or Ir, yield the neutral title compounds of which (ReS4)[RhCl(C5 Me5)] and (/a-WS4)[IrCl(C5 Me5) ] 2 could be crystallographically characterized. The molecules contain nearly tetrahedral M'S4 units and rhodium(III) or iridium(III) centers with piano stool geometry. Weak intermolecular (M)C1--H(Me) interactions are observed in the crystals. Vibrational and elec­ tronic spectra are in agreement with the structures, illustrating p—d charge transfer interactions between the sulfide or chloride donors and the d° or d6 metal acceptor centers, respectively. Oxidation and reduction of the compounds occur completely irreversibly. 
  Reference    Z. Naturforsch. 56b, 940—946 (2001); eingegangen am 29. März 2001 
  Published    2001 
  Keywords    Iridium Compounds, Rhodium Compounds, Tetrathiometallates 
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 TEI-XML for    default:Reihe_B/56/ZNB-2001-56b-0940.pdf 
 Identifier    ZNB-2001-56b-0940 
 Volume    56