| | 1 | Author
| M. Athias, O. Senge, KevinM. Smith | Requires cookie* | | | Title
| -octaethyl-porphodimethene-thallium(III) Chloride  | | | | Abstract
| The crystal structure of the title com pound was determined in order to obtain structural information on a tetrapyrrole bearing meso-oxo-functions. C36H 4,N 40 2T1C1 • C H 3OH, P 1, a = 10.358(2), b = 12.344(3), c = 15.490(3) Ä, a = 84.36(2)°, ß = 78.53(2)°, y = 82.26(2)°, V = 1918.2(7) Ä3, Z = 2, 130 K, R = 0.04 for 6749 reflections with I > 4er(I). The structure consists of the penta-coordinated thallium ligated by the four nitrogens of the porphodimethene ligand and a chloride in the axial position. The central macrocycle shows some degree of ruffling with the carbonyl groups pointing slightly above and below the mean plane of the molecule. | | | |
Reference
| Z. Naturforsch. 47b, 837—841 (1992); received December 5 1991 | | | |
Published
| 1992 | | | |
Keywords
| /F ebruary 28, 1992 Crystal Structure, 5, 15-Dioxo-porphodimethene, Tetrapyrroles, Oxoporphyrins | | | |
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| default:Reihe_B/47/ZNB-1992-47b-0837.pdf | | | | Identifier
| ZNB-1992-47b-0837 | | | | Volume
| 47 | |
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