| | 1 | Author
| Wilfried Bubenheim, Ulrich Müller | Requires cookie* | | | Title
| Tetraphenylphosphonium- tris(tetrasulfido)stannat, (PPh4)2[Sn(S4)3] Tetraphenylphosphonium Tris-tetrasulfido- stannate, (PPh4)2[Sn(S4)3]  | | | | Abstract
| PPh4[SnCl3] reacts with Na2S4 in acetonitrile to give the title compound as one of the products. Its crystal structure was determined by X-ray diffrac tion (R = 0.071 for 3288 reflexions). Crystal data: monoclinic, P2JC, Z = 4, a = 1301.2(3), b = 1139.1(2), c = 3476.2(7) pm, ß = 97.82(3)°. (PPh4)2[Sn(S4)3] is isotypic with (PPh4)2[Sn(Se4)3] and contains [Sn(S4)3]2-ions in which three tetra-sulfido groups are chelating an octahedrally coordi nated tin atom. | | | |
Reference
| Z. Naturforsch. 50b, 1135 (1995); eingegangen am 27. Januar 1995 | | | |
Published
| 1995 | | | |
Keywords
| Tetraphenylphosphonium tris-tetrasulfido-stannate, Synthesis, Crystal Structure | | | |
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