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'Tetraphenylphosphonium tris tetrasulfido stannate' in keywords
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1995 (1)
1Author    Wilfried Bubenheim, Ulrich MüllerRequires cookie*
 Title    Tetraphenylphosphonium- tris(tetrasulfido)stannat, (PPh4)2[Sn(S4)3] Tetraphenylphosphonium Tris-tetrasulfido- stannate, (PPh4)2[Sn(S4)3]  
 Abstract    PPh4[SnCl3] reacts with Na2S4 in acetonitrile to give the title compound as one of the products. Its crystal structure was determined by X-ray diffrac­ tion (R = 0.071 for 3288 reflexions). Crystal data: monoclinic, P2JC, Z = 4, a = 1301.2(3), b = 1139.1(2), c = 3476.2(7) pm, ß = 97.82(3)°. (PPh4)2[Sn(S4)3] is isotypic with (PPh4)2[Sn(Se4)3] and contains [Sn(S4)3]2-ions in which three tetra-sulfido groups are chelating an octahedrally coordi­ nated tin atom. 
  Reference    Z. Naturforsch. 50b, 1135 (1995); eingegangen am 27. Januar 1995 
  Published    1995 
  Keywords    Tetraphenylphosphonium tris-tetrasulfido-stannate, Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1135_n.pdf 
 Identifier    ZNB-1995-50b-1135_n 
 Volume    50