| | 1 | Author
| Herbert Schumann, Heinrich Neumann | Requires cookie* | | | Title
| Organometallphosphin-substituierte Übergangsmetallkomplexe, XXVII [1] Reaktionen von Pentacarbonylmangan-und Pentacarbonylrheniumbromid mit Organoelement(rVb)phosphinen Organometalphosphine-Substituted Transition Metal Complexes, XXVII [1] Reactions of Pentacarbonylmanganese-and Pentacarbonylrheniumbromide with Organoelement(IVb) Phosphines  | | | | Abstract
| The reactions of pentacarbonyl manganese bromide and pentacarbonyl rhenium bromide with di(ter£-butyl)trimethylsilyl phosphine, teri-butyl-bis(trimethylsilyl)-, -(germyl)-, -(stannyl) phosphine, as well as with tris(trimethylsilyl)-, -(germyl)-, and -(stannyl) phosphine result in the elimination of one CO ligand and the formation either of corresponding bromo-tetracarbonyl(organometalphosphine)manganese or -rhenium complexes or of corresponding octacarbonyl-bis(/z-organometalphosphido)dimanganese or -dirhenium complexes. The IR, NMR, and Mössbauer spectra are reported and discussed. | | | |
Reference
| Z. Naturforsch. 36b, 708—712 (1981); eingegangen am 27. Februar 1981 | | | |
Published
| 1981 | | | |
Keywords
| Organometal Phosphines, Tetracarbonylmanganese Complexes, Tetracarbonylrhenium Complexes, NMR Spectra, Mössbauer Spectra | | | |
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| default:Reihe_B/36/ZNB-1981-36b-0708.pdf | | | | Identifier
| ZNB-1981-36b-0708 | | | | Volume
| 36 | |
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