| | 1 | Author
| Tsutomu Okuda, Yoshihiro Kinoshita, Hiromitsu Terao, Koji Yamada | Requires cookie* | | | Title
| Structure and Bonding of Bromoantimonate (III) Complexes with Unusual Valency by Means of NQR and Powder X-Ray Diffraction  | | | | Abstract
| NQR and powder X-ray diffraction were observed for several bromoantimonate (III) complexes which contain C"H2n+ jNF^ (n = 1 -3) or (C"H2lt + 1)2N H 2 (n = 1 -4) as a cation. The bond character, anion structure, crystal structure, and phase transition are discussed on the basis of the three-center-four-electron bond. A good correlation was found between the halogen NQR frequency and the Sb-X bond length. | | | |
Reference
| Z. Naturforsch. 49a, 185—192 (1994); received July 23 1993 | | | |
Published
| 1994 | | | |
Keywords
| 81Br NQR, Temperature dependence, Phase transition, Crystal structure | | | |
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| default:Reihe_A/49/ZNA-1994-49a-0185.pdf | | | | Identifier
| ZNA-1994-49a-0185 | | | | Volume
| 49 | |
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