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'Tautomerism' in keywords Facet   Publication Year 1980  [X]
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1980[X]
1Author    K. C. Dash, A. Schmidpeter++, H. Schmidbaur+Requires cookie*
 Title    Gold Complexes of a P-Coordinate Cyclotriphosphazene [1,2]  
 Abstract    Contrary to the reports on the coordination oi copper (I) to N/P-ambidentate cyclotri-phosphazenes, gold (I), gold (III) and dimethylgoldf 111) chloride are found to become exclusively P-coordinated to the prototype ligand 2-methyl-4,4,6,6-tetraphenylcyclotri-phosphazene (1). The P-H proton is transferred to an adjacent nitrogen atom of the heterocycle. According to temperature dependent NMR spectra, the AuCl and the AuClß complexes are fluxional molecules or ions, resp., with a rapid proton transfer between P-NH-P and P = N-P functions. The behaviour is similar to that of related palladium and platinum complexes, reported previously. 
  Reference    Z. Naturforsch. 35b, 1286—1288 (1980); eingegangen am 9. Juni 1980 
  Published    1980 
  Keywords    Gold Complexes, Cyclotriphosphazenes, N/P-Ambidentate System, Tautomerism 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1286.pdf 
 Identifier    ZNB-1980-35b-1286 
 Volume    35