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1979 (1)
1Author    W. Stoeger, A. RabenauRequires cookie*
 Title    Darstellung, Eigenschaften und Kristallstruktur von TlgAu^j 0 Preparation, Properties, and Crystal Structure of TI6AU2I10  
 Abstract    TI6AU2I10 forms black crystals with a golden luster. In a closed system the temperature of decomposition is 276 °C. In vacuum or under inert gas TlßA^Iio decomposes above 65 °C forming 1 mol I2. Above 180 °C a second mol I2 is formed giving Til and gold. The space group is P 62c with the lattice constants a = 10.569 and c = 13.431 A and Z = 2. TI6AU2I10 is built up by a framework of Tlßlß with channels parallel to the c-axis. These channels contain Au + mainly with a trigonal planar coordination or linear IJj-polyiodide ions and I -ions, resp. 
  Reference    Z. Naturforsch. 34b, 685—692 (1979); eingegangen am 24. Januar 1979 
  Published    1979 
  Keywords    X-ray, Structure Determination, Polyhalides, T1 Halides, Au Halides 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-0685.pdf 
 Identifier    ZNB-1979-34b-0685 
 Volume    34