1 | Author | Manfred Zabel, Klaus-Jürgen Range | Requires cookie* |
Title | Ternäre Phasen im System Eisen-Thallium-Schwefel Ternary Phases in the System Iron Thallium-Sulfur ![]() | ||
Abstract | The Compound TlFeS2 was synthesized from TIS/Fe/S-mixtures. Crystals are mono-clinic (space group C2/m) with a = 1164.4(6) pm, b = 530.8(3) pm, c = 1050.9(5) pm, ß = 144.58° and Z = 4. The structure comprises [FeS2 -]oo-chains parallel b, built from edge-shared FeS-i-tetrahedra. Relations between TlFeS2 and orthorhombic CsFeS2 are discussed. Tetragonal or monoclinic distorted tetragonal ternary phases occur with composition FeaTV^ (2.6 <x <3.6). | ||
Reference | (Z. Naturforsch. 34b, 1—6 [1979]; eingegangen am 23. August 1978) | ||
Published | 1979 | ||
Keywords | System Iron-Thallium-Sulfur, Ternary Compounds, Crystal Structure, Phase Transitions | ||
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