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'Synthesis' in keywords Facet   section ZfN Section B:Volume 030  [X]
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1975 (3)
1Author    Requires cookie*
 Title    Übergangsmetall-Antimon(HI)bromide  
 Abstract    T ransition M etal-A n tim on y(III) Brom ides W o l f g a n g M a l i s c h und P e t e r P a n s t e r In stitu t Antim The reaction of SbBr3 with the complex metal carbonyl anions [jz-C5H 5(CO)3M]Na (M = Mo, W) leads to the formation of transition metal antimony bromides 7r-C5H 5(CO)3M -SbBr2, which can be further metallated, yielding the stable species jr-C5H 5(CO)3M -Sb-M / (CO)n7t-C5H 5 (M = M' = Mo, W) 
  Reference    (Z. Naturforsch. 30b, 229—234 [1975]; eingegangen am 16. Dezember 1974) 
  Published    1975 
  Keywords    ony-transition Metal Compounds, Synthesis, Coordination, Oxidation 
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 TEI-XML for    default:Reihe_B/30/ZNB-1975-30b-0229.pdf 
 Identifier    ZNB-1975-30b-0229 
 Volume    30 
2Author    Requires cookie*
 Title    Darstellung und Charakterisierung eines Di-w-amido-und von Di-^-hydroxokomplexen der  
 Abstract    Zusammensetzung [n>C5H5 Cr(NO)(NH2) ] 2 bzw. [7t-C5H 5Cr(NO)(OH)]2 (H 20) n (n = 0 -2) S ynthesis and C haracterization o f a D i-^-am ido-and D i-^-hydroxo Com plexes o f C om position [7r-C5H 5C r(N O)(N H 2)]2 and |>r-C5H 5Cr(NO)(OH)]2 • (H 20)" {n = 0 -2), R esp ectively G e r h a r d H o c h , H a n s -E c k a r d S a s s e und M a n f r e d L. Z i e g l e r The title compounds have been synthesized and characterized by elementary analysis, IR and NMR methods and their mass spectra. The compound [7i-C5H 5 Cr(NO)(NH2) ]2 is a di-^-amido complex, [jr-C5H 5Cr(NO)(OH) ] 2 -2 H 20 is its hydroxo analogon, elevation of the temperature causes the stepwise loss of the two water molecules yielding [7r-C5H 5 Cr(N0)(0 H)]2 -H 2 0 and [7i-C5H 5Cr(NO)(OH)]2. 
  Reference    (Z. Naturforsch. 30b, 704—709 [1975]; eingegangen am 24. Juni 1975) 
  Published    1975 
  Keywords    Synthesis, Characterization, Di-^-amido Complexes, Di-^-hydroxo Complexes 
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 TEI-XML for    default:Reihe_B/30/ZNB-1975-30b-0704.pdf 
 Identifier    ZNB-1975-30b-0704 
 Volume    30 
3Author    A. O., W.J SRequires cookie*
 Title    Axial Preference of Methylthio Substituent in Dioxaphosphorinanyl Ring System  
 Abstract    The spatial disposition of a 2-methvlthio group in the 4-m ethyl-1,3,2-dioxaphosphorin­ anyl ring system was studied by stereochemical correlation, X H, 13C and 31P NMR. It has been established that a CH3S-group prefers an axial orientation much more strongly than does a m ethoxy group. 
  Reference    (Z. Naturforsch. 30b, 430—436 [1975]; received February 4 1975) 
  Published    1975 
  Keywords    ) 2-Methylthio-l, 3, 2-dioxaphosphorinans, Synthesis, Spectral Characteristics, Conformation 
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 TEI-XML for    default:Reihe_B/30/ZNB-1975-30b-0430.pdf 
 Identifier    ZNB-1975-30b-0430 
 Volume    30