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1996 (1)
1Author    KlausA. Ngerm Aier, A.Lexander Sladek, Hubert SchmRequires cookie*
 Title    Gold(I) Complexes of Chiral Secondary Phosphines  
 Abstract    The reaction of (dimethylsulfide)gold(I) chloride and bromide with methyl(phenyl)phosphine in tetrahydrofuran affords high yields of the colorless, crystalline, chiral complexes [M e(Ph)HP]AuCl/Br (la, b). Treatment of la with potassium iodide in thf leads to a conversion into the corresponding iodide [Me(Ph)HP] Aul (lc). The compounds were characterized by their analytical and spectroscopic data, and the crystal structures of la, b have been determined. The two compounds are isomorphous. In the lattice the monomers form chain-like supramolecular aggregates through auriophilic A u-A u contacts. The chains contain both enantiomers following the sequence . . R S R S R S.., with the individual components related by crystal symmetry. 
  Reference    Z. Naturforsch. 51b, 1671—1674 (1996); received September 17 1996 
  Published    1996 
  Keywords    Gold(I) Complexes, Chiral Phosphine Ligands, Auriophilicity, Supramolecular Aggregates 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-1671.pdf 
 Identifier    ZNB-1996-51b-1671 
 Volume    51