| | 1 | Author
| FrankW. Heinem, Helmut Hartung, NadjaM. Aier3, HermannM. Atschiner3 | Requires cookie* | | | Title
| Molekül-und Kristallstruktur der Verbindung 8-(n-Butylamino- phenyl-methyliden)  | | | | Abstract
| -l,2,3?4,5,6,7-heptathiocan Molecular and Crystal Structure of 8-(«-Butylamino-phenyl-methylidene)-l,2,3,4,5,6,7-heptathiocane By the reaction of acetophenone with sulfur and primary amines yellow-coloured crystals of the title compound are formed. It crystallizes in the monoclinic space group P 2 x!n with lattice constants a = 1309.9(2) pm, b = 926.5(2) pm, c -1582.2(2) pm and ß -114.00(1)°. The structure of the eight-membered heptathiocane ring is characterized by a crown confor mation. The range of the S -S distances [204.4(1)-207.3(1) pm], the S -S -S bond angles [107.2(1) — 109.0(1)°] and the S-S-S-S torsion angles [93.2(1)-97.7(1)°] is comparable to those observed in a-, ß-and y-sulfur. | | | |
Reference
| Z. Naturforsch. 49b, 1063—1066 (1994); eingegangen am 3. Februar 1994 | | | |
Published
| 1994 | | | |
Keywords
| Heptathiocane, Acetophenone, Sulfur, Crystal Structure, Crown Conformation | | | |
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| default:Reihe_B/49/ZNB-1994-49b-1063.pdf | | | | Identifier
| ZNB-1994-49b-1063 | | | | Volume
| 49 | |
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