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1988[X]
1Author    Lothar Weber, Georg Meine, Roland Boese, Norbert NiederprümRequires cookie*
 Title    Übergangsmetall-substituierte Diphosphene, XIV [1]  
 Abstract    Zur Reaktivität des Diphosphenylkomplexes (i/ 5 -C 5 Me5)(CO) 2 Fe—P=P—Ar (Ar = 2,4,6-r-Bu 3 C 6 H 2) gegenüber Schwefel, Selen und Tellur. Synthese und Struktur des ersten Thioxo-A s -diphosphenyl-Komplexes (!7 5 -C 5 Me 5)(CO) 2 Fe-P(=S)(=P-Ar) Transition Metal Substituted Diphosphenes, XIV [1] On the Reactivity of the Diphosphenyl Complex (?; ; '-C5Me5)(CO) 2 Fe-P=P-Ar (Ar = 2,4,6-J-Bu 3 C 6 H 2) towards Sulfur, Selenium, and Tellurium. Synthesis and X-Ray Structure Analysis of the First Thioxo-A 5 -diphosphenyl Complex (>/ 5 -C 5 Me 5) (CO) 2 Fe -P(=S)(=P -Ar) The diphosphenyl complex (?7 5 -C 5 Me 5)(CO) 2 Fe-P=P-Ar (la) (Ar = 2,4,6-rm-Bu 3 C 6 H 2) reacts with an equimolar amount of sulfur to yield the first thioxo-A 5 -diphosphenyl com-plex (/7 5 -C 5 Me 5)(CO) 2 Fe-P(= S) = P-Ar (2). Heating of 2 in boiling benzene affords the metal functionalized thiadiphosphirane 3. Similarily the selenoxo-A 5 -diphosphenyl complex (^ 5 -C 5 Me 5)(CO) 2 Fe —P(=Se) = P—Ar (5) and selena-diphosphirane 6 are synthesized. The prod-ucts have been characterized by elemental analysis as well as by spectroscopic data (IR, 'H, 13 C, 31 P NMR, MS). The molecular structure of 2 has been elucidated by single crystal X-ray analysis. 
  Reference    Z. Naturforsch. 43b, 715—721 (1988); eingegangen am 26. Oktober 1987 
  Published    1988 
  Keywords    Diphosphenyl Complex, Sulfur, Selenium, Tellurium, X-Ray Analysis 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0715.pdf 
 Identifier    ZNB-1988-43b-0715 
 Volume    43