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1Author    H. Erbert, W. Roesky, Nasreddine Benm, Oham Ed, Klaus Keller, Nayla Keweloh, M. Athias, N. Oltem Eyer, GeorgeM. SheldrickRequires cookie*
 Title    Synthesis and Crystal Structure of Seven-M em bered Sulfur Nitrogen Rings Containing Carbon  
 Abstract    The reaction of C1SCF2CF2SC1 and (Me3SiN)2SR2 proceeds with formation of the seven-mem-bered ring compounds 4a, R = CH3, and 4b, R = C2H 5. 4a was shown by an X-ray structure determination to contain a non-planar ring system. 
  Reference    Z. Naturforsch. 42b, 1249—1252 (1987); eingegangen am 5. Mai 1987 
  Published    1987 
  Keywords    Crystal Structure, Sulfur, Nitrogen 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-1249.pdf 
 Identifier    ZNB-1987-42b-1249 
 Volume    42 
2Author    MarcoH. Klingele, Gunther Steinfeld, Berthold KerstingRequires cookie*
 Title    Synthesis and Coordination Chemistry of Novel Binucleating Macrocyclic Ligands with Amine-thioether and Amine-thiophenolate Donor Functions  
 Abstract    The ability of the aromatic tetraaldehyde l,2-bis(4-rm-butyl-2,6-diformylphenylsulfanyl)-ethane (1) to function as a precursor in the preparation of binucleating hexaamine-dithiolate lig­ ands has been investigated. Reductive amination of compound 1 with bis(aminoethyl)amine un­ der medium-dilution conditions affords the macrobicyclic hexaamine-dithioether compound L 1. Deprotection of the [1+2] condensation product gives the corresponding 24-membered hexa-amine-dithiophenol ligand H2L2. The formulation of L 1 as a macrobicyclic amine-thioether was confirmed by an X-ray crystal structure determination of the tetranuclear nickel(II) complex of L 1, [{ (L jN iiC lili^ -C l^K B P h ;) (2b). The formulation of the doubly deprotonated form (L2)2-of H2L2 as a 24-membered amine-thiophenolate ligand was confirmed by an X-ray crystal structure determination of the dinuclear cobalt(III) complex, [(L2)Com(^-OH)](C1 0 4) 2 • Cl (3). The preparation and the crystal structures of the new compounds are described. 
  Reference    Z. Naturforsch. 56b, 901—907 (2001); received June 5 2001 
  Published    2001 
  Keywords    Macrocyclic Ligands, Nitrogen, Sulfur 
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 TEI-XML for    default:Reihe_B/56/ZNB-2001-56b-0901.pdf 
 Identifier    ZNB-2001-56b-0901 
 Volume    56 
3Author    W.Requires cookie*
 Title    R eaktionen des Tris(trim ethylsilyl)hydroxylam ins m it Schwefel-und Phosphoroxidfluoriden Reactions of Tris-trimethylsilyl Hydroxylamine with Oxifluorides of Sulfur and Phosphorus  
 Abstract    e r n e r L i d y , Ch r is t o f J ä c k h u n d W o l f g a n g S u n d e r m e y e r Anorganisch-Chemisches In s titu t der U n iv ersität H eidelberg The new com pounds R 3 S i-0 -N S 0 F 2 and R 3 S i-0 -N (S iR 3)P 0 F 2 [R = CH3] are ob­ ta in ed by cleavage reaction of Si-N -bonds in tris(trim ethylsilyl)hydroxylam ine by OSF4 and O P F 3, respectively. 
  Reference    (Z. Naturforsch. 32b, 595—596 [1977]; eingegangen am 13. Mai 1976/21. Februar 1977) 
  Published    1977 
  Keywords    Silyl H ydroxylam ine, Preparation, Oxifluorides, Sulfur, Phosphorus 
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 TEI-XML for    default:Reihe_B/32/ZNB-1977-32b-0595_n.pdf 
 Identifier    ZNB-1977-32b-0595_n 
 Volume    32 
4Author    ChrL. TeskeRequires cookie*
 Title    Darstellung, Kristallstrukturdaten und Eigenschaften der quaternären Thiostannate(IV) BaZnSnS4 und BaMnSnS4 Preparation, Crystal Data and Properties of the Quaternary Thiostannates(IV) BaZnSnS4 and BaMnSnS4  
 Abstract    BaZnSnS4 and BaMnSnS4 were prepared for the first time and the atomic positions of the crystal structure were refined. Both compounds crystallize isotypically with BaCdSnS4 [1]. Space group C^-Fdd2 (No. 43) orthorhombic. BaZnSnS4: a = 2196,4; b = 2150,4; c = 1270,i pm; BaMnSnS4: a = 2173,i; b = 2144,9; c -1259,i. 
  Reference    Z. Naturforsch. 35b, 509—510 (1980); eingegangen am 30. Oktober 1979 
  Published    1980 
  Keywords    Crystal Structure, Interatomic Distances, Zinc, Manganese, Sulfur 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0509_n.pdf 
 Identifier    ZNB-1980-35b-0509_n 
 Volume    35 
5Author    HeinzP. Fritz, OttoS. HuberRequires cookie*
 Title    Die Elektrolyse von P4/HS03F-Miscliiingeii The Electrolysis of P4/HSO3F Mixtures  
 Abstract    The electrolysis of P4/HSO3F mixtures does not yield detectable phosphorus-polyatomic cations; the intense coloration of the electrolyte is due to the known sulfur polyatomic cations originating from decomposition of HSO3F. 
  Reference    Z. Naturforsch. 35b, 530—532 (1980); eingegangen am 4. Januar 1980 
  Published    1980 
  Keywords    Anodic Oxidation, White Phosphorus, Sulfur, Polyatomic Cations 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0530.pdf 
 Identifier    ZNB-1980-35b-0530 
 Volume    35 
6Author    HerbertW. Roesky, Pierre Schäfer, Mathias Noltemeyer, GeorgeM. SheldrickRequires cookie*
 Title    Zur Darstellung und Struktur des 1.3-Dichloro-5-N.N-dimethylamino-1.3-dithia-2.4.6-triazins Synthesis and Structure of l,3-Dichloro-5-N,N-dimethylamino-l,3-dithia-2,4,6-triazine  
 Abstract    The six membered ring of composition (CH3)2NCN3S2Cl2 8 a was prepared from N,N-dimethylguanidinhydrochloride and trithiadiazindichloride. 3 a was characterized on the basis of mass, 1 H, 13 C NMR spectra and X-ray structure analysis. Crystals of 3 a are monoclinic, space group P2i/c, with a — 660.3(6), b = 834.5(7), c = 1774.7(15) pm, ß = 112.83(6)° and Z = 4. The C2N unit lies approximately in the plane of the [-CNSNSN-] ring, with both Cl atoms on the same side of the ring. 
  Reference    Z. Naturforsch. 38b, 347—349 (1983); eingegangen am 16. September 1982 
  Published    1983 
  Keywords    Six Membered Ring, Carbon, Sulfur, Nitrogen, X-Ray Structure 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0347.pdf 
 Identifier    ZNB-1983-38b-0347 
 Volume    38 
7Author    Lothar Weber, Georg Meine, Roland Boese, Norbert NiederprümRequires cookie*
 Title    Übergangsmetall-substituierte Diphosphene, XIV [1]  
 Abstract    Zur Reaktivität des Diphosphenylkomplexes (i/ 5 -C 5 Me5)(CO) 2 Fe—P=P—Ar (Ar = 2,4,6-r-Bu 3 C 6 H 2) gegenüber Schwefel, Selen und Tellur. Synthese und Struktur des ersten Thioxo-A s -diphosphenyl-Komplexes (!7 5 -C 5 Me 5)(CO) 2 Fe-P(=S)(=P-Ar) Transition Metal Substituted Diphosphenes, XIV [1] On the Reactivity of the Diphosphenyl Complex (?; ; '-C5Me5)(CO) 2 Fe-P=P-Ar (Ar = 2,4,6-J-Bu 3 C 6 H 2) towards Sulfur, Selenium, and Tellurium. Synthesis and X-Ray Structure Analysis of the First Thioxo-A 5 -diphosphenyl Complex (>/ 5 -C 5 Me 5) (CO) 2 Fe -P(=S)(=P -Ar) The diphosphenyl complex (?7 5 -C 5 Me 5)(CO) 2 Fe-P=P-Ar (la) (Ar = 2,4,6-rm-Bu 3 C 6 H 2) reacts with an equimolar amount of sulfur to yield the first thioxo-A 5 -diphosphenyl com-plex (/7 5 -C 5 Me 5)(CO) 2 Fe-P(= S) = P-Ar (2). Heating of 2 in boiling benzene affords the metal functionalized thiadiphosphirane 3. Similarily the selenoxo-A 5 -diphosphenyl complex (^ 5 -C 5 Me 5)(CO) 2 Fe —P(=Se) = P—Ar (5) and selena-diphosphirane 6 are synthesized. The prod-ucts have been characterized by elemental analysis as well as by spectroscopic data (IR, 'H, 13 C, 31 P NMR, MS). The molecular structure of 2 has been elucidated by single crystal X-ray analysis. 
  Reference    Z. Naturforsch. 43b, 715—721 (1988); eingegangen am 26. Oktober 1987 
  Published    1988 
  Keywords    Diphosphenyl Complex, Sulfur, Selenium, Tellurium, X-Ray Analysis 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0715.pdf 
 Identifier    ZNB-1988-43b-0715 
 Volume    43 
8Author    Anja Edelmann, Sally Brooker, N. Orbert Bertel, M. Athias Noltemeyer, H. Erbert, W. Roesky, GeorgeM. Sheldrick, FrankT. EdelmannRequires cookie*
 Title    Strukturuntersuchungen an Diaryldichalkogeniden: Die Molekülstrukturen von |2  
 Abstract    ,4,6-(CF3)3C6H 2S]2,12,4,6-M e3C6H 2TeI2 und |2-M e2N-4,6-(CF3)2C6H 2Te]2 Structural Investigations of Diaryl Dichalcogenides: The Molecular Structures o f [2,4,6-(CF3)3C6HiS],, [2,4,6-Me3C6H ?Te]2 and [2-Me2N-4,6-(CF3)2C6H 2Te]2 The molecular structures o f [2,4,6-(CF3)3C6H 2S]2 (1), [2,4,6-M e3C6H 2Te]2 (2) and [2-Me2N -4,6-(C F 3)2C6H2Te]2 (3) have been determined by X-ray diffraction. Crystal data: 1: orthorhombic, space group P 2,2,2,, Z = 4, a = 822.3(2), b = 1029.2(2), c = 2526.6(5) pm (2343 observed independent reflexions, R = 0.042); 2: orthorhom bic, space group Iba2, Z = 8, a = 1546.5(2), b = 1578.4(2), c = 1483.9(1) pm (2051 observed independent reflexions, R = 0.030); 3: m onoclinic, space group P 2,/c, Z = 4, a = 1118.7(1), b = 1536.5(2), c = 1492.6(2) pm, ß = 98.97(1)° (3033 observed independent reflexions, R = 0.025). 
  Reference    Z. Naturforsch. 47b, 305 (1992); eingegangen am 12. Ju li/9. September 1991 
  Published    1992 
  Keywords    Sulfur, Tellurium, Disulfides, Ditellurides, X -R ay 
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 TEI-XML for    default:Reihe_B/47/ZNB-1992-47b-0305.pdf 
 Identifier    ZNB-1992-47b-0305 
 Volume    47 
9Author    FrankW. Heinem, Helmut Hartung, NadjaM. Aier3, HermannM. Atschiner3Requires cookie*
 Title    Molekül-und Kristallstruktur der Verbindung 8-(n-Butylamino- phenyl-methyliden)  
 Abstract    -l,2,3?4,5,6,7-heptathiocan Molecular and Crystal Structure of 8-(«-Butylamino-phenyl-methylidene)-l,2,3,4,5,6,7-heptathiocane By the reaction of acetophenone with sulfur and primary amines yellow-coloured crystals of the title compound are formed. It crystallizes in the monoclinic space group P 2 x!n with lattice constants a = 1309.9(2) pm, b = 926.5(2) pm, c -1582.2(2) pm and ß -114.00(1)°. The structure of the eight-membered heptathiocane ring is characterized by a crown confor­ mation. The range of the S -S distances [204.4(1)-207.3(1) pm], the S -S -S bond angles [107.2(1) — 109.0(1)°] and the S-S-S-S torsion angles [93.2(1)-97.7(1)°] is comparable to those observed in a-, ß-and y-sulfur. 
  Reference    Z. Naturforsch. 49b, 1063—1066 (1994); eingegangen am 3. Februar 1994 
  Published    1994 
  Keywords    Heptathiocane, Acetophenone, Sulfur, Crystal Structure, Crown Conformation 
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 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-1063.pdf 
 Identifier    ZNB-1994-49b-1063 
 Volume    49 
10Author    Jun-H, G. Chou, Thom As, B. RauchfussRequires cookie*
 Title    c4 s82- 4 -. and CjtfSjg Intermediates in the Synthesis of PoIy(Carbon Sulfide)  
  Reference    Z. Naturforsch. 52b, 1549—1552 (1997); received August 11 1997 
  Published    1997 
  Keywords    Sulfur, Carbon Sulfides, Inorganic Polymer, Polysulfide, Thiophene 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-1549_n.pdf 
 Identifier    ZNB-1997-52b-1549_n 
 Volume    52 
11Author    KurtO. Klepp, Ferdinand Fabian, *. Sonderdruckanforderungen, Prof Kurt, O. KleppRequires cookie*
 Title    Darstellung und Kristallstruktur von Rb6Sn2S7 New Chalcogenometallates with Binuclear Anions, I: Preparation and Crystal Structure of Rb6Sn2S7  
 Abstract    Colorless crystals of the new thiostannate Rb6Sn2S7 were obtained by reacting a stoichio­ metric melt of Rb2S, Sn and S at 700°C. The compound is orthorhombic, oP60, s.g. f '2,2,2, (No. 19) with a = 9.982(4), b = 13.45(1), c = 15.20(1) A; Z = 4. The crystal structure was determined from diffractometer data and refined to a conventional R of 0.043 (1380 Fo's, 137 variables). The crystal structure contains dimeric anions, [Sn2S7]2 -, which are built up by slightly distorted SnS4 tetrahedra sharing a common sulfur atom. The mean Sn-S bond length calculates as 2.384 Ä, the bond angle on the bridging S is 110.4°. The structure contains six independent Rb-cations which are coordinated to 5-6 sulfur atoms in irregular configurations. Neue Chalkogenometallate mit binuklearen Anionen, I: 
  Reference    Z. Naturforsch. 54b, 1505—1509 (1999); eingegangen am 13. September 1999 
  Published    1999 
  Keywords    Crystal Structure, Chalcogenides, Thiostannates, Rubidium, Tin, Sulfur 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-1505.pdf 
 Identifier    ZNB-1999-54b-1505 
 Volume    54 
12Author    A. Müller, S. Pohl, M. Dartmann, J. P. Cohen, J. M. Bennett, R. M. KirchnerRequires cookie*
 Title    Crystal Structure of (NH4)2[Mo3S(S2)6] Containing the Novel Isolated Cluster [MO3S13] 2  
 Abstract    The novel tri-nuclear metal-sulfur cluster [Mo3S(S2)6] 2 ~ can be obtained as its am-monium salt by the reaction of a Mo iv containing aqueous solutions with polysulfide. Its crystal and molecular structure has been determined by a single crystal X-ray study. The crystals are monoclinic (space group Cm, with a = 11.577(6) A, b = 16.448(7) Ä, c = 5.716(2) Ä, ß = 117.30(3)°, V = 967.2 A 3 , Z = 2, dexpti. = 2.54(2) g/cm 3 , dcai = 2.54 g/cm 3). The structure consists of isolated [Mo3S(S2)6] 2_ units, with three Mo atoms at the vertices of a triangle. There are bridging as well as terminal S2 2 ~-ligands lying above and below the Mo3-plane (bond distances: Mo-Mo = 2.722 A, Mo-S(terminal) = 2.435, Mo-S(bridging) = 2.452, Mo3-S = 2.353(4) A and S-S = 2.04 A (mean values)). Transition metal sulfur clusters are model com-pounds of bioinorganic interest [1, 2]. Isolated binary sulfur clusters were unknown until recently, though several halogen cluster compounds were reported. We were able to isolate the novel com-pound (NH4)2[Mo3S(S2)6] containing bridging as well as terminal S2 2_ -ligands in the molybdenum-sulfur-cluster anion [2]. In this paper the crystal structure of the compound is reported. Experimental 
  Reference    Z. Naturforsch. 34b, 434—436 (1979); received August 28/November 10 1978 
  Published    1979 
  Keywords    Crystal Structure, Molybdenum, Sulfur, Cluster, Metal-Metal Bond, Disulfide Diatomic Ligands 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-0434.pdf 
 Identifier    ZNB-1979-34b-0434 
 Volume    34 
13Author    H. Erbert, W. Roesky, H. Artm, Ut HofmRequires cookie*
 Title    Cyclisation of Bis(2,2,2-trifluoroethoxy)-l,2-diim inoethane with Sulfur, Selenium, Phosphorus, and Arsenic Chlorides  
 Abstract    By the reaction of cyanogen with 2,2,2-trifluoroethanol in the presence o f a base catalyst, 
  Reference    Z. Naturforsch. 39b, 1315 (1984) 
  Published    1984 
  Keywords    eingegangen 1984 Cyanogen, Five-mem bered Rings, Phosphorus, Sulfur, Selenium 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-1315.pdf 
 Identifier    ZNB-1984-39b-1315 
 Volume    39 
14Author    Z. NaturforschRequires cookie*
 Title    S o lv a to  
 Abstract    th erm a le D a r ste llu n g u nd S tru k tu r v o n [M e 4N ] 2[A s 6S 10] und [M e 4N ] 2 [A s 4S 7 ], d e m er ste n T h io a r se n a t(III) m it A s S 4 tr ig o n a len B ip yram id en S o lv a to th e rm a l S y nthesis an d S tru c tu re o f th e T h io a rs e n a te s (III) [M e4N ]2[A s6S 10] a n d [M e4N ]2[A s4S7], th e F irst T h io a rs e n a te (III) w ith ¥/-A sS 4 T rigonal B ip y ram id s V io la V ater, W illiam S. S held rick * The tetramethylammonium thioarsenate(III) [Me4N]2[As6S 10] (1) has been prepared toge­ ther with the minor product [Me4N]2[As4S7] (2) by reaction of [Me4N]Cl with As2S3 and Na2S in acetonitrile at 115 °C. The polymeric anion of 1 consists of adjacent i[A s3S5'] chains linked together into a i[A s6S102"] double chain through planar As2S2 rings involving As atoms of every second constituent ring-shaped A s3S6 building unit. A relatively undistorted V'-AsS4 trigonal bipyramidal geometry is observed for the participating As atoms. Individual A s3S6 units are linked by bridging AsS3 pyramids into the zweier single chains i[A s4S72"] in 2. 
  Reference    Z. Naturforsch. 52b, 1119—1124 (1997); eingegangen am 17. Juni 1997 
  Published    1997 
  Keywords    Arsenic, Sulfur, Thioarsenates(III), Solvatothermal Synthesis, Structure-Direction 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-1119.pdf 
 Identifier    ZNB-1997-52b-1119 
 Volume    52 
15Author    B. Erthold Kersting, G. Unther SteinfeldRequires cookie*
 Title    On the M etalation o f 2,6-Dimethyl-4-ter/-butyl-thiophenol  
  Reference    Z. Naturforsch. 53b, 1239—1240 (1998); received August 5 1998 
  Published    1998 
  Keywords    M etalation, 2, 6-Dim ethyl-4-rm -butyl-thiophenol, Lithium, Sulfur 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-1239_n.pdf 
 Identifier    ZNB-1998-53b-1239_n 
 Volume    53 
16Author    Barbara Wenzel, Peter StrauchRequires cookie*
 Title    Synthesis, Structural and EPR Investigations on Bis(tetraphenylphosphonium)- bis(l,2-dithiosquarato)oxovanadate(IV), (Ph4P)2[VO(dtsq)2]  
 Abstract    The molecular structure and EPR studies of bis(tetraphenylphosphonium)bis(1,2-dithiosquarato)oxovanadate(IV) are reported. (Ph4P)2[VO(dtsq)2] crystallizes in the mono­ clinic spaceogroup P2,/n with the unit cell parameters a = 10,9820(2), b = 15,4620(3), c = 14,5050(3) Ä, ß = 95,700(8)°, Z = 2. The g and hyperfine coupling tensors Av obtained from the EPR spectra in liquid and frozen solution are used to characterize the properties of the molecular orbital containing the unpaired electron and are compared to those obtained from EHT-MO calculations. 
  Reference    Z. Naturforsch. 54b, 165—170 (1999); eingegangen am 18. September 1998 
  Published    1999 
  Keywords    Sulfur, Oxovanadate(IV), Synthesis, EPR Data, Crystal Structure 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-0165.pdf 
 Identifier    ZNB-1999-54b-0165 
 Volume    54