| 1 | Author
| Ralf Steudel, Jürgen Steidel, Norbert Rautenberg | Requires cookie* | | Title
| Röntgenstrukturanalyse und Schwingungsspektren yon Trischwefeldistickstoffdioxid, S3N202 [1] X-ray Structural Analysis and Vibrational Spectra of Trisulfurdinitrogendioxide, S3N2O2 [1]  | | | Abstract
| A redetermination of the crystal and molecular structure of the chain-like molecule S(NSO)2 resulted in the following molecular parameters: d(SO) = 146.5(2), d(S = N) = 153.4(2), d(S-N) = 165.7(2) pm, bond angles OSN = 117.5(1)°, SNS = 123.6(2)°, and NSN = 97.2(1)°, torsion angles OSNS = -0.3(2)°, and SNSN = -177.7(2)° (molecular symmetry C2). Infrared and Raman spectra of S(NSO)2 are reported and assigned; there is no evidence for conformational changes on dissolution of crystalline S( | | |
Reference
| Z. Naturforsch. 35b, 792—796 (1980); eingegangen am 5. März 1980 | | |
Published
| 1980 | | |
Keywords
| Sulfur Nitrogen Compounds, Structure, Vibrational Spectra | | |
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| default:Reihe_B/35/ZNB-1980-35b-0792.pdf | | | Identifier
| ZNB-1980-35b-0792 | | | Volume
| 35 | |
3 | Author
| Zu Sulfoxiden, Ralf Steudel, Fritz Rose | Requires cookie* | | Title
| von Schwefel-Stickstoff-Verbindungen Oxidation of Sulfur-Nitrogen Compounds to Sulfoxides by Peroxyacids  | | | Abstract
| Trifluoroperoxyacetic acid reacts in 80% yield with (S7N)2S to give colorless crystals of the known (SvN^SO, and with S7NH to give the formerly unknown unstable hepta-sulfurimide 3-oxide, S7NHO, the properties and vibrational spectra of which are reported. | | |
Reference
| (Z. Naturforsch. 33b, 122—123 [1978]; eingegangen am 7. November 1977) | | |
Published
| 1978 | | |
Keywords
| Sulfur-nitrogen Compounds, Oxidation, Trifluoroperoxyacetic Acid, Heptasulfur Imide, Thionyl Compounds | | |
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| default:Reihe_B/33/ZNB-1978-33b-0122_n.pdf | | | Identifier
| ZNB-1978-33b-0122_n | | | Volume
| 33 | |
4 | Author
| HerbertW. Roesky, Erwin Wehner | Requires cookie* | | Title
| Reactions of 3,4-Dichloro-l,2,5-thiadiazol  | | | Abstract
| SN2C2CI2 prepared from (CN)2 and S2CI2 reacts with BCI3, SbCls and SO3 to yield the 1:1 adducts, TiCU forms an 1:2 adduct. The adducts were characterized on the basis of IR and Raman spectra. SN2C2CI2 is alkylated with (C2H5)30 + BF4~ at one of the nitrogen atoms. The results are compared with adducts of S2N2CO with Lewis acids. | | |
Reference
| Z. Naturforsch. 36b, 1247—1250 (1981); eingegangen am 22. Juni 1981 | | |
Published
| 1981 | | |
Keywords
| Sulfur-Nitrogen Compounds, Lewis Acids, Raman Spectra, IR Spectra | | |
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| default:Reihe_B/36/ZNB-1981-36b-1247.pdf | | | Identifier
| ZNB-1981-36b-1247 | | | Volume
| 36 | |
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