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1985 (2)
1984 (1)
1Author    Rüdiger Kniep, LutzK. Örte, Dietrich MootzRequires cookie*
 Title    Phasenbeziehungen im System Schwefel—Chlor sowie Kristallstrukturen von SC12 und SC14 [1] Phase Relations in the System Sulfur—Chlorine and Crystal Structures of SC12 and SC14  
 Abstract    From new DT A and powder diffraction measurements in the binary system sulfur-chlorine a consistent construction of the melting diagram for the region 50—100 atom-% Cl was possible. It contains sulfur chlorides of the elemental ratios 1:1, 1:2, 1:3, and 1:4 as the stable intermediate phases, which melt at -8 0 °C (congr.), —125 °C (incongr.), —75 °C (incongr.) and — 34 °C (congr.), respectively. SCI is S2C12 as characterized by its crystal structure by R. Kniep, L. Korte 
  Reference    Z. Naturforsch. 39b, 305 (1984); eingegangen am 27. September 1984 
  Published    1984 
  Keywords    Phase Relations, Sulfur Halides, Crystal Structure 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-0305.pdf 
 Identifier    ZNB-1984-39b-0305 
 Volume    39 
2Author    Rolf Minkwitz, Klaus Jänichen, Herbert Prenzel, Volker WölfelRequires cookie*
 Title    Beiträge zur Chemie der Schwefelhalogenide, 6 [1] Untersuchungen an Trichlorsulfonium(IV)-Salzen Contributions to the Chemistry of Sulfur Halides, 6 [1] Investigations on Trichlorosulfonium(IV) Salts  
 Abstract    The crystal structure of SCl 3 + AsF 6 ~ is reported. The mean S-Cl stretching frequency v of the SC1 3 + cations, weighted according to the degree of degeneration, in the different SC1 3 + X~ salts is directly proportional to the mean S-Cl distance r scl , the force constant f sci and the sulfur.. .anion distance (C1 3 S + .. .X"). That SC1 3 + C1" should be isostructural with PC1 4 ~, the large variation in the S-Cl stretching frequencies in the SC1 3 + X~ salts is due to cation-anion interaction forces. 
  Reference    (Z. Naturforsch. 40b, 53—56 [1985]; eingegangen am 4. Juli/10. Oktober 1984) 
  Published    1985 
  Keywords    Crystal Structure, Bonding and Force Constants, Sulfur Halides 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0053.pdf 
 Identifier    ZNB-1985-40b-0053 
 Volume    40 
3Author    Rolf Minkwitz, UlrikeN. Aß, Armin Radünz, Hans PreutRequires cookie*
 Title    Beiträge zur Chemie der Schwefelhalogenide, 9 [1]  
 Abstract    Trifhiormethyldichlorsulfonium(IV)-hexafluoroarsenat(V) Contributions to the Chemistry of Sulfur Halides, 9 [1] Trifluorom ethyldichlorosulfonium (IV) H exafluoroarsenate(V) The synthesis of CF3SC12+A sF6_ is reported. The sulfonium salt is characterised by IR , Ram an, l9F and l3C NMR spectroscopy. The vibrational assignment is based on a Cs model for the cation and assisted by a normal coordinate analysis. The crystal structure has been determ ined from three-dimensional diffractom eter data at —133 K. The structural data for the cation are: C -F = 128.8(5) pm, C -S = 197,8(3) pm, S -C l -195,9(1) pm and F -C -F -111,8(3)°, C l -S -C l = 104,22(5)°, C -S -C l -99,8(1)°. 
  Reference    Z. Naturforsch. 40b, 1123—1129 (1985); eingegangen am 6. Mai 1985 
  Published    1985 
  Keywords    Preparation, Crystal Structure, Bonding and Force C onstants, Sulfur Halides 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-1123.pdf 
 Identifier    ZNB-1985-40b-1123 
 Volume    40