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'Sulfur Diimides' in keywords Facet   section ZfN Section B  [X]
Facet   Publication Year 2001  [X]
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1Author    Max Herberhold, Silke Gerstmann, Bernd WrackmeyerRequires cookie*
 Title    Ethylboration of Stannyl-Substituted Sulfur Diimides  
 Abstract    Bis(sulfurdiimido)tin compounds of the type R2Sn[(NSN)'Bu]2 [R = Me (2a), Et (2b)] re­ act with triethylborane Et^B by rearrangement and N-ethylation to give the novel amino-borane derivatives R2Sn[N('Bu)SN(Et)BEt2]2 (5a, b), in the same way as "Bu3Sn(NSN)'Bu (1) reacts with Et.^B to give "Bu3Sn[N('Bu)SN(Et)BEt2] (4). In contrast, 2c (R = 'Bu) and tris(sulfurdiimido)tin compounds RSn[(NSN)'Bu]3 [R = Me (3a), "Bu (3d)] react with Et3B mainly by Sn-and S-ethylation, accompanied by extensive decomposition. 'H, "B , 13C, 15N and 119Sn NMR spectroscopy served for the structural assignment in solution. 
  Reference    Z. Naturforsch. 56b, 342—346 (2001); received August 15 2000 
  Published    2001 
  Keywords    Aminoboranes, Organoboration, Sulfur Diimides 
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 TEI-XML for    default:Reihe_B/56/ZNB-2001-56b-0342.pdf 
 Identifier    ZNB-2001-56b-0342 
 Volume    56