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1979 (1)
1Author    B. Engelen, C. FreiburgRequires cookie*
 Title    Kristallstruktur von Mangan(II)sulfit-Trihydrat, a-MnS03 * 3 H20 Crystal Structure of Manganese(II)sulfite Trihydrate, a-MnS03 * 3 H2O  
 Abstract    The structure of a-MnS03 • 3 H20, space group P2i/n, Z = 4, Dm = 2.42, Dx = 2.425gcm-3, a = 6.6501(3), b = 8.9065(4), c = 8.7925(4) Ä, ß=* 96.105(3)°, was solved by the Patterson method and refined by Fourier and least-squares methods. All H atoms were located. The final R's are 2.1/3.2% for the 1749 observed/2280 measured reflexions. Coordination of Mn is octahedral involving O atoms from three water molecules and three different sulfite groups. MnOß octahedra are linked through sulfite sulfur. The Mn-0 distances range from 2.149(2) to 2.314(2) A. The S-0 distances of the sulfite group are 1.529(2), 1.529(2) and 1.544(2) A. The first two are elongated by one, the latter by two H bonds. The O-S-O angles are 103.25(9), 104.18(9) and 104.35(9)°. 
  Reference    Z. Naturforsch. 34b, 1495—1499 (1979); eingegangen am 9. Juli 1979 
  Published    1979 
  Keywords    X-ray, Sulfites, Sulfite Hydrates 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-1495.pdf 
 Identifier    ZNB-1979-34b-1495 
 Volume    34