| | 1 | Author
| B. Engelen, C. Freiburg | Requires cookie* | | | Title
| Kristallstruktur von Mangan(II)sulfit-Trihydrat, a-MnS03 * 3 H20 Crystal Structure of Manganese(II)sulfite Trihydrate, a-MnS03 * 3 H2O  | | | | Abstract
| The structure of a-MnS03 • 3 H20, space group P2i/n, Z = 4, Dm = 2.42, Dx = 2.425gcm-3, a = 6.6501(3), b = 8.9065(4), c = 8.7925(4) Ä, ß=* 96.105(3)°, was solved by the Patterson method and refined by Fourier and least-squares methods. All H atoms were located. The final R's are 2.1/3.2% for the 1749 observed/2280 measured reflexions. Coordination of Mn is octahedral involving O atoms from three water molecules and three different sulfite groups. MnOß octahedra are linked through sulfite sulfur. The Mn-0 distances range from 2.149(2) to 2.314(2) A. The S-0 distances of the sulfite group are 1.529(2), 1.529(2) and 1.544(2) A. The first two are elongated by one, the latter by two H bonds. The O-S-O angles are 103.25(9), 104.18(9) and 104.35(9)°. | | | |
Reference
| Z. Naturforsch. 34b, 1495—1499 (1979); eingegangen am 9. Juli 1979 | | | |
Published
| 1979 | | | |
Keywords
| X-ray, Sulfites, Sulfite Hydrates | | | |
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| default:Reihe_B/34/ZNB-1979-34b-1495.pdf | | | | Identifier
| ZNB-1979-34b-1495 | | | | Volume
| 34 | |
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