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1995 (1)
1Author    Z. NaturforschRequires cookie*
 Title    Hexacarbonyldieisen-stabilisierte Sulfimid-Derivate, Fe2(CO)6(w-SNR)  
 Abstract    Hexacarbonyl diiron com plexes of N-substituted sulfimides (SN R) have been obtained from the parent tetrahedrane, Fe2(C O)6(//-SN H) (1), by deprotonation to give the anion Fe2(C O)6(/i-SN _) (2) and subsequent reaction with either trialkyloxonium or carbenium tetrafluoroborates. The new aza-diferra-thia-tetrahedranes, Fe2(C O)6(w-SNR) (R = CH3 (3a), C2H5 (3b), CPh3 (3c), cyc/o-C^Ph^ (3d), cyclo-C 7H 7 (3e), and cyc/o-(C7H 7)M (CO)3 with M = Cr (3f), Mo (3g), W (3h)) were characterized by their 'H and 13C NM R as well as their IR and MS spectra. The molecular structure of Fe2(C O)6[S N -cy c/o -C 7H 7M o(C O)3] (3g) has been determined by X-ray diffraction. 
  Reference    Z. Naturforsch. 50b, 1252—1556 (1995); eingegangen am 29. Dezem ber 1994 
  Published    1995 
  Keywords    Sulfimide Complexes, Hexacarbonyl Diiron Complexes, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1252.pdf 
 Identifier    ZNB-1995-50b-1252 
 Volume    50