| | 1 | Author
| Horst Kunkely, AmD. Vogler | Requires cookie* | | | Title
| Photoreactivity of Titanocene Pentasulfide  | | | | Abstract
| The electronic spectrum o f Cp2TiSs shows a long-wavelength absorption at Am ax = 492 nm which is assigned to the lowest-energy S52~ ^ T i IV ligand-to-metal charge transfer (L M C T) transition. The photolysis o f the complex in C H 2CI2 leads to the formation o f Cp2T iC l2 and elemental sulfur. It is suggested that L M C T excitation initiates a reductive elimination with the extrusion o f S5 while the reduced titanocene is reoxidized by the solvent. | | | |
Reference
| Z. Naturforsch. 53b, 224—226 (1998); received December 12 1997 | | | |
Published
| 1998 | | | |
Keywords
| Charge Transfer, Titanium Complexes, Sulfide Complexes, Photochemistry | | | |
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| default:Reihe_B/53/ZNB-1998-53b-0224.pdf | | | | Identifier
| ZNB-1998-53b-0224 | | | | Volume
| 53 | |
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