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1998 (1)
1Author    Horst Kunkely, AmD. VoglerRequires cookie*
 Title    Photoreactivity of Titanocene Pentasulfide  
 Abstract    The electronic spectrum o f Cp2TiSs shows a long-wavelength absorption at Am ax = 492 nm which is assigned to the lowest-energy S52~ ^ T i IV ligand-to-metal charge transfer (L M C T) transition. The photolysis o f the complex in C H 2CI2 leads to the formation o f Cp2T iC l2 and elemental sulfur. It is suggested that L M C T excitation initiates a reductive elimination with the extrusion o f S5 while the reduced titanocene is reoxidized by the solvent. 
  Reference    Z. Naturforsch. 53b, 224—226 (1998); received December 12 1997 
  Published    1998 
  Keywords    Charge Transfer, Titanium Complexes, Sulfide Complexes, Photochemistry 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-0224.pdf 
 Identifier    ZNB-1998-53b-0224 
 Volume    53