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'Stereochemistry' in keywords Facet   Publication Year 1995  [X]
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1Author    Stefan Fuchs, H. Ubert SchmidbaurRequires cookie*
 Title    Phosphonic Acid Anhydrides [R P 0 2]": Oligomerization and Structure  
 Abstract    The phosphonic acid anhydrides of the general formula [R P 0 2]" have been prepared with R = Me, Et, z-Pr, r-Bu, and Ph from the corresponding phosphonic acids and their chlorides and esters. Mass spectrometric data indicate that the trimers are the dominant oligomers for all five systems. According to their NMR spectra, the methyl and r-butyl compounds have a symmetrical (C3v) structure with equivalent RP groups, while the ethyl, /-propyl and phenyl homologues have the Cs structure with non-equivalent PR groups in the ratio 1:2. 
  Reference    Z. Naturforsch. 50b, 855—858 (1995); received November 11 1994 
  Published    1995 
  Keywords    Organophosphonic Acid Anhydrides, Phosphonic Acid Anhydrides, Stereochemistry, NM R Spectra 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-0855.pdf 
 Identifier    ZNB-1995-50b-0855 
 Volume    50