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2001 (1)
1Author    Shao-Yi Wu, Wen-Chen ZhengRequires cookie*
 Title    Investigations of the EPR Parameters and Local Structures for Two Tetragonal Cr3* Centers in NH4C1 Crystal  
 Abstract    In this paper, the zero-field splittings D and g factors g», g± at room temperature for two tetragonal Cr3+ centers in NH4Cl:Cr3+ crystal have been investigated by a two-spin-orbit (S.O)-parameter model, in which both the contribution due to the S.O. coupling of central d3 ion and that of ligands are considered. From the investigations, the signs of zero-field splitting and the local structures of both centers are ob­ tained. The electron paramagnetic resonance parameters D, g^ and g± of both centers are also explained. 
  Reference    Z. Naturforsch. 56a, 326—3 (2001); received February 1 2001 
  Published    2001 
  Keywords    Spin-orbit Coupling, Electron Paramagnetic Resonance (EPR), Crystal-field Theory, Cr3+, NH4CI4 PACS: 7630Fc, 7170Ch 
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 TEI-XML for    default:Reihe_A/56/ZNA-2001-56a-0326.pdf 
 Identifier    ZNA-2001-56a-0326 
 Volume    56