| | 1 | Author
| G., R. Ia, N. Ie | Requires cookie* | | | Title
| Investigation of Inductive Effects on the Transphosphorylation Reaction of Spin-Labeled Phosphoryl Imidazolides, Part  | | | | Abstract
| Spin-labeled phosphoryl imidazolides 3, 6 , and 7 were prepared and compared to the unsubstituted compound 1 in reactivity towards hydroxy and amino compounds. The transphorphorylation reaction of compounds 3 and 6 was slower than that of 1. The reaction of compound 6 was selective towards amines since no reaction occurred with hydroxy compounds. The reaction of compounds 7 was slow with hydroxy compounds and rapid with amines at room temperature. The transphorphorylation reaction of 1 was rapid with both hydroxy and amino compounds at 50-55 °C. | | | |
Reference
| (Z. Naturforsch. 32b, 1182—1188 [1977]; received July 4 1977) | | | |
Published
| 1977 | | | |
Keywords
| Spin-Labeling, Nitroxyl, Imidazoles, Spin-Labeled Phosphates, Spin-Labeled Phosphoroamidates | | | |
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| default:Reihe_B/32/ZNB-1977-32b-1182.pdf | | | | Identifier
| ZNB-1977-32b-1182 | | | | Volume
| 32 | |
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