| | 1 | Author
| RichardP. Kreher, Gerald Dyker, WilhelmP. Neumann | Requires cookie* | | | Title
| Structure and Reactivity of Isoannelated Heterocyclic Systems with Ann-and (4n+2)jr-Electrons, XII [1] 2-terr-Butyl-4-methyl-2,4-dihydropyrrolo[3,4-b]indoles: Tricyclic Hetarenes with Isoannelated Pyrrole Rings  | | | |
Reference
| Z. Naturforsch. 42b, 473—477 (1987); eingegangen am 14. November 1986 | | | |
Published
| 1987 | | | |
Keywords
| Substituted 2, 3-Dihydropyrrolo[3, 4-b]indoles, Synthesis, Isolation, Spectroscopic Properties, Cycloaddition Reactions | | | |
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| default:Reihe_B/42/ZNB-1987-42b-0473.pdf | | | | Identifier
| ZNB-1987-42b-0473 | | | | Volume
| 42 | |
| 2 | Author
| RichardP. Kreher, Thomas Hildebrand | Requires cookie* | | | Title
| Structure and Reactivity of Isoannellated Heterocyclic Systems with 4nji-and (4/7+2);r-Electrons, XIV [1] Tri-and Tetracyclic Hetarenes with Localized or Delocalized Pyrrole Units | | | | Abstract
| 2,7-Di-/er/-butyl-2,7-dihydro-benzo[ 1,2-c:3,4-c']dipyrrole (2b) and 2,5,8-Tri-rm-butyl-5.8-di-hydro-2H-benzo[l,2-c:3,4-c':5,6-c"]tripyrrole (3b) have been prepared by acetolysis of the cor-responding tri-and tetracyclic N-oxides, isolated in crystallinic form and characterized by spec-troscopic data. The scope of the N-oxide route is documented and the existence of benzo-annellated pyrroles is proofed. The stabilizing effect of the tert-butyl group is presumably sup-ported by the vicinal annellated heterocycles. | | | |
Reference
| (Z. Naturforsch. 43b, 125—131 [1988]; eingegangen am 15. September 1987) | | | |
Published
| 1988 | | | |
Keywords
| Benzo-annellated Di-and Tripyrroles, Synthesis, Isolation, Spectroscopic Properties, Cycloaddition Reactions | | | |
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| default:Reihe_B/43/ZNB-1988-43b-0125.pdf | | | | Identifier
| ZNB-1988-43b-0125 | | | | Volume
| 43 | |
| 3 | Author
| A.Ntoni Keller, Ludmila Szterenberg | Requires cookie* | | | Title
| Dinitrosylmolybdenum Complexes with Anion Ligands Coordinating by Oxygen Atoms. Synthesis, Electronic Structure and Olefin Metathesis Activity of Carboxylato-Dinitrosyl-Molybdenum Complexes | | | | Abstract
| The new carboxylato-dinitrosyl-molybdenum complexes o f the formula: [M o(N O)2(0 2CMe)2] • M eOH , N a2[M o(N O)2(0 2CM e)4] and M o(N O)2(0 2CPh)2 have been synthesized. Their structure was resolved on the basis o f spectroscopic investigations ('H N M R , IR, U V -V IS). Catalytic activity o f these complexes in olefin metathesis reaction was also examined. The electronic structure o f dinitrosyl-molybdenum complexes with ligands coordinating by oxygen atom s was calculated for the example o f the di-and tetra-acetato-dinitrosyl-molybden-um com plexes using the Fenske-Hall and IN D O methods. To interpret the spectroscopic properties (U V -V IS) within the method o f interaction configuration, the electronic structure o f the excited states was calculated. | | | |
Reference
| Z. Naturforsch. 47b, 1469—1476 (1992); received December 13 1991 | | | |
Published
| 1992 | | | |
Keywords
| D initrosylm olybdenum Complexes, Carboxylato Complexes, Electronic Structure Calculation, Spectroscopic Properties, Olefin M etathesis | | | |
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| default:Reihe_B/47/ZNB-1992-47b-1469.pdf | | | | Identifier
| ZNB-1992-47b-1469 | | | | Volume
| 47 | |
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