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'Solid Solution' in keywords Facet   Publication Year 1993  [X]
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1Author    Roger Blachnik, Peter Lönnecke, Jürgen NußRequires cookie*
 Title    Gläser und Verbindungen im System P4S4-A s 4S4-A s 4Se4-P 4Se4 Glass and Com pounds in the System P4S4-A s 4S4-A s 4Se4-P 4Se4  
 Abstract    Glas forming regions and glass temperatures o f the system P4S4-A s 4S4-A s 4Se4-P 4Se4 have been determined by thermoanalytical and X-ray methods. In the whole system crystalline sam­ ples have been obtained by annealing. From the pure phases A s4S4 and P4Se4 broad regions o f solid solutions extend into the system. In the P4S4 corner the form ation o f A 4B3 (A = P, As; B = S, Se) molecules is observed. As with A 4B3 m olecules, a stepwise substitution o f P by As atoms, and o f S by Se atom s is possible. All molecules o f the series P4_"As"S4 and A s4S4_"Sen (n = 0, 1, 2, 3, 4) were detected by 31P N M R and/or mass spectroscopy. 
  Reference    Z. Naturforsch. 48b, 1175—1180 (1993); eingegangen am 19. Mai 1993 
  Published    1993 
  Keywords    Phosphorus Arsenic Chalcogenides, Chalcogenide Glasses, Solid Solutions 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-1175.pdf 
 Identifier    ZNB-1993-48b-1175 
 Volume    48