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'Sodium Triflate' in keywords Facet   section ZfN Section B  [X]
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1998 (1)
1Author    Gabriele Korus, Martin JansenRequires cookie*
 Title    Kristallstruktur von Natriumtrifluormethylsulfonat- Trifluormethylsulfonsäure (1/3) Studies on Sodium Trifluoromethanesulfonate. Crystal Structure of Sodium Trifluoromethanesulfonate-Trifluoromethanesulfonic Acid (1/3)  
 Abstract    Single crystals of sodium trifluoromethanesulfonate-trifluoromethanesulfonic acid (1/3) (N aS 0 3CF3 • 3 H S 0 3CF3) have been prepared by reaction of sodium trifluoromethanesulfonate with anhydrous trifluoromethanesulfonic acid at 60 °C. N aS 0 3CF3 • 3 H S 0 3CF3 crystallizes in space group 1 2 ^ (No. 199) with a = 16.210(1) A, Z = 8. Sodium is coordinated by six oxygen atoms from six different trifluoromethanesulfonic acid molecules, each acid molecu­ le connecting two sodium ions. The 3-dimensional network resulting from the edge sharing octahedra corresponds to the cubic (10, 3) net, not realised otherwise, so far. The trifluorome­ thanesulfonate anion is bonded to three trifluoromethanesulfonic acid molecules by hydrogen bonds. 
  Reference    Z. Naturforsch. 53b, 438—442 (1998); eingegangen am 19. Dezember 1997 
  Published    1998 
  Keywords    Sodium Trifluoromethanesulfonate, Sodium Triflate, Trifluoromethanesulfonic Acid, Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-0438.pdf 
 Identifier    ZNB-1998-53b-0438 
 Volume    53