1 | Author | Wolfgang Blase, G.Erhard Cordier | Requires cookie* |
Title | D ie Kristallstruktur von Na3Ga8Sn3 und die Interpretation der Bindungsverhältnisse auf der Basis der Wadeschen Regeln und des Zintlkonzeptes The Crystal Structure of Na3G a8Sn3 and the Interpretation of its Chemical Bonding According to W ade's Rules and the Zintl Concept ![]() | ||
Abstract | The crystal structure of Na3G a8Sn3 (a = 1532.7(7), b = 890.7(6), c = 1224.9(8) pm; ß = 129.6(2)°, space group C2/m) contains G a l2 icosahedra and puckered layers of condensed six-m em bered Ga/Sn rings, which are interconnected by additional Ga/Sn atoms to a three-dim en sional framework. The Na content of the com pound correlates with the num ber of electrons necessary for a stable electron configuration in the anionic partial structure. | ||
Reference | Z. Naturforsch. 44b, 1011—1014 (1989); eingegangen am 10. April 1989 | ||
Published | 1989 | ||
Keywords | Sodium -Gallium -Stannides, Crystal Structure, W ade's Rules, Zintl Concept | ||
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