| | 1 | Author
| Berthold Brazel, Rudolf Hoppe | Requires cookie* | | | Title
| Über Oxoplumbate(IV) Die Kristallstruktur von HT-Li2Pb03 [1] The Crystal Structure of HT-Li2Pb03 [1]  | | | | Abstract
| Single crystals of HT-Li2Pb03 have been prepared by heating of mixtures of Rb2Pb03 and Li20 [Ag-cylinders, 600 °C, 100 d]. The structure determination [1005 symmetry independent l0(hkl), R = 5.85%, Rw = 5.35%, confirms space group C2/c with a = 548.60(16), b = 949.51(22), c = 1027.35(27) pm, ß = 100.11(3)°, drö = 6.78 g • cm-3 , dpyk = 6.80 g • cm-3 , Z — 8. The NaCl-type structure variant is characterized by alter-nating layers of Li+ and Pb 4+ /Li + cations, which are all octahedrally coordinated. Effective Coordination Numbers, ECoN are calculated via Mean Fictive Ionic Radii, MEFIR. | | | |
Reference
| Z. Naturforsch. 38b, 661—664 (1983); eingegangen am 15. Februar 1983 | | | |
Published
| 1983 | | | |
Keywords
| Lithiumoxoplumbate(IV) (High Temperature Form), Single Crystal Preparation, Structure | | | |
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| default:Reihe_B/38/ZNB-1983-38b-0661.pdf | | | | Identifier
| ZNB-1983-38b-0661 | | | | Volume
| 38 | |
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