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'Silyl M igration' in keywords
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1991 (1)
1Author    WolfgangA. Herrm, DieterW M Arz, Eberhardt HerdtweckRequires cookie*
 Title    Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, LXXXIX+. Selektive Bildung eines Imidometallsiloxans aus einem sek. Silylamin Multiple Bonds between M ain G roup Elements and Transition Metals, LX X X IX +. Selective Form ation of an Im idometallosiloxane from a sec. Silylamine  
 Abstract    Reaction o f (N-trimethylsilyl)-a:-aminopicolin with the rhenium(V) oxohalogenide (j75-C5M e5)ReO Cl2 (Me = C H 3) exemplifies a simple, clean synthesis o f im ido-m etallo-siloxanes, com pounds o f the structure R3S iO -M = N -R '. The com pound (//5-C5M e5)ReCl[OSi(CH3)3](N C H 2-2 -C 5H4N) thus formed under HC1 elimination has a square-pyramidal molecular structure (single crystal X-ray diffraction). 
  Reference    Z. Naturforsch. 46b, 747 (1991); eingegangen am 7. September 1990 
  Published    1991 
  Keywords    Imido, Rhenium, Structure, Silyl M igration 
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 TEI-XML for    default:Reihe_B/46/ZNB-1991-46b-0747.pdf 
 Identifier    ZNB-1991-46b-0747 
 Volume    46