| | 1 | Author
| P. Jutzi, C. Batz, A. Mutluay | Requires cookie* | | | Title
| Eightfold Functionalization of the Octasilsesquioxane Core  | | | | Abstract
| Eightfold functionalized octasilsesquioxanes (R8Si80 12) are synthesized using the hydro silylation method. D ifferent types of groups R, consisting of an (-0 -S i M e 2(CH 2)2) spacer unit and various terminal units (-C H 2(C2M e)B 1oH1o, -C 5H 3M eM n(CO)3, -S iM e2C5H 4FeC5H 5 , -S iM e2Cl, -SiM eC l2, -S i(O E t)3) have been introduced. The hydro silylation products have been characterized by 'H, 13C, 29Si NMR and infrared spectroscopy and elemental analysis. The redox properties of the ferrocenyl substituted compound have been studied by cyclovoltammetry. Results | | | |
Reference
| Z. Naturforsch. 49b, 1689—1692 (1994); received May 17 1994 | | | |
Published
| 1994 | | | |
Keywords
| Octasilsesquioxanes, Hydrosilylation, Siloxanes, Ferrocenes, Carboranes | | | |
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| default:Reihe_B/49/ZNB-1994-49b-1689.pdf | | | | Identifier
| ZNB-1994-49b-1689 | | | | Volume
| 49 | |
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