| | 1 | Author
| Feng-Quan Liu, Hans-Georg Schmidt, M. Athias Noltemeyer, Cristina Freire-Erdbrügger, GeorgeM. Sheldrick, HerbertW. Roesky | Requires cookie* | | | Title
| Synthesis and Structure of Eight-Membered Titanium Containing Siloxane Rings  | | | | Abstract
| The preparation by different methods o f the eight-membered ring com pounds (R 'X T i0S iR 220) 2 is reported: (2: R' = C5H 5, X=C1, R2=/Bu; 3: R '= N (S iM e3)2, X=C1, R 2=/Bu; 4: R' = C 5M e5, X = C1, R 2=Ph; 6: R' = X = N E t2, R 2=fB u). The six-membered ring Ph2SiO[OTiC5M e5(Cl)]2 5 is formed together with 4 by the reaction o f C5M e5TiCl3 and Ph2Si(OLi)2. Com pounds 2 and 4 have been characterized by X-ray structural analysis. | | | |
Reference
| Z. Naturforsch. 47b, 1085—1090 (1992); received March 2 1992 | | | |
Published
| 1992 | | | |
Keywords
| Organotitanium, Amides, Siloxanes, Eight-Membered Rings | | | |
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| default:Reihe_B/47/ZNB-1992-47b-1085.pdf | | | | Identifier
| ZNB-1992-47b-1085 | | | | Volume
| 47 | |
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