| | 1 | Author
| Reinhold Tacke, Haryanto Linoh, Burghard Stumpf, Wolf-Rainer Abraham, Klaus Kieslich, Ludger Ernst | Requires cookie* | | | Title
| Mikrobiologische Umwandlung von Silicium-Yerbindungen: Enantioselektive Reduktion von Acetessigsäure-(trimethylsilylalkyl)estern und deren Carba-Analoga Microbiological Transformation of Silicon Compounds: Enantioselective Reduction of Trimethylsilylalkyl Acetoacetates and their Carba-Analogues  | | | | Abstract
| The trimethylsilylalkyl acetoacetates 1 b and 2 b as well as their carba analogues 1 a and 2 a have been reduced microbiologically by Kloeckera corticis (ATCC 20109), leading to the corresponding (+)-3(£)-hydroxybutanoates 3b, 4b, 3a, and 4a. The enantiomeric purity was found to be 80% (3a, 3b, 4b) and 65% (4a), respectively. The reduction of lb and 2b is -to our knowledge -the first example for a controlled microbiological transformation of organosilicon substrates. | | | |
Reference
| Z. Naturforsch. 38b, 616—620 (1983); eingegangen am 8. Dezember 1982 | | | |
Published
| 1983 | | | |
Keywords
| Silicon Compounds, Microbiological Transformation, Enantioselective Reduction | | | |
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| default:Reihe_B/38/ZNB-1983-38b-0616.pdf | | | | Identifier
| ZNB-1983-38b-0616 | | | | Volume
| 38 | |
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