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'Side on Coordination' in keywords Facet   Publication Year 1995  [X]
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1Author    Christian Drost, Carsten Jäger, Uwe Klingebiel, Christina Freire-Erdbrügger, Regine Herbst-Irm, M. Er, Artina SchäferRequires cookie*
 Title    Lithium-[N-di-terr-butylfluorsilyl-N' ,N ' -dimethyl-hydrazid] - Synthese, Kristallstruktur und Reaktivität Lithium (N-di-te/'f-butylfluorosilyl-N',N'-dimethyl)hydrazide - Synthesis, Crystal Structure and Reactivity  
 Abstract    Di-terf-butyldifluorosilane reacts with N-lithium -N',N'-dimethylhydrazine in a molar ratio 1:1 to yield the N-di-ferf-butylfluorosilyl-N',N'-dimethylhydrazine 1. The lithium derivative of 1 (2) forms a dimer with the nitrogen atoms coordinated "side-on" to the lithium atoms. The silylation with M e3SiCl gives product 3. Heating 2 in a vacuum leads to the cyclo-disilazane derivative 4. A bis(hydrazino)fluoroborane (5) is obtained in the reaction of 2 with trifluoroborane-etherate. 
  Reference    (Z. Naturforsch. 50b, 76—8 [1995]; eingegangen am 18. Juli 1994) 
  Published    1995 
  Keywords    Fluorosilylhyrazines, Lithium-Derivative, Crystal Structure, Side-on Coordination 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-0076.pdf 
 Identifier    ZNB-1995-50b-0076 
 Volume    50