| 1 | Author
| Erwin Riedel, Norbert Pfeil | Requires cookie* | | Title
| Verteilung und Valenz der Kationen in Spinellsystemen mit Eisen und Vanadium, II Röntgenographische Untersuchung, Seebeck Koeffizienten, Mößbauer-und IR-Spektren der Mischkristallreihen Fe2V04-ZnV204 und Fe2V04-ZnFe204 Distribution and Valence of the Cations in Spinel Systems with Iron and Vanadium, II X-ray Investigation, Seebeck Coefficients, Mössbauer and IR Spectra of the Solid Solutions Fe2V04-ZnV204 and Fe2V04-ZnFe204  | | | Abstract
| The spinel series Fe2V04-ZnV204 and Fe2V04-ZnFe204 have been prepared and investigated. The lattice constants and Mössbauer spectra lead to a distribution of cations which proves that Fe2V04 is a partially inverse spinel with Fe(II) and Fe(III) on the tetrahedral site. The Seebeck effect is interpreted with a model of both tetrahedral and octahedral conduction based on charge hopping. | | |
Reference
| Z. Naturforsch. 35b, 1261—1267 (1980); eingegangen am 2. Juni 1980 | | |
Published
| 1980 | | |
Keywords
| Zinc-Iron-Vanadium Spineis, Mössbauer Spectroscopy, Seebeck Effect, Charge Hopping, Cation Distribution | | |
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| default:Reihe_B/35/ZNB-1980-35b-1261.pdf | | | Identifier
| ZNB-1980-35b-1261 | | | Volume
| 35 | |
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