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'Secondary Acid Amide Groups' in keywords Facet   Publication Year 1981  [X]
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1Author    ThF. Zafiropoulos, S. P. Perlepes, P. V. Ioannou, J. M. Tsangaris, A. G. GalinosRequires cookie*
 Title    Non Deprotonated Metal Complexes of the Bis-amide Tetradentate Ligand N,N' -(Dipicolyl) -1,8-naphthylenediamine  
 Abstract    Complexes of the general formula M(LH2)Cl2 • 2 H2O, where LH2 = N,N'-(dipicolyl)-1,8-naphthylenediamine and M = Mn, Ni and Cu, have been prepared. None of the metal ions used promote amide deprotonation on coordination: LH2 acts as a tetradentate ligand. Distorted octahedral stereochemistries for the complexes in the solid state have been proposed utilising microanalyses, magnetic susceptibilities, molar conductance measure-ments and IR and visible spectral data. The Ni(II) complex exhibits evidence of a poly-meric structure. 
  Reference    (Z. Naturforsch. 36b, 87 [1981]; received July 14 1980) 
  Published    1981 
  Keywords    N, N'-(Dipicolyl)-l, 8-naphthylenediamine, Bis-amide Tetradentate Ligand, Secondary Acid Amide Groups, Non-Deprotonated Complexes, IR Spectra 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0087.pdf 
 Identifier    ZNB-1981-36b-0087 
 Volume    36