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1999 (1)
1Author    Max Herberhold, Silke Köppl, Wolfgang MiliusRequires cookie*
 Title    Mixed-Sandwich rflry Vanadium Complexes. The Molecular Structure of (?75-2-Methyl-indenyl)-(777-cycloheptatrienyl)-vanadium  
 Abstract    The diamagnetic halfsandwich complexes [V(?^7-C7H7)(CO)3] and [V(7/5-L5)(CO)4] have been used as intermediates in the conversion of hexcarbonylvanadium, V(CO)6, to the para­ magnetic trovacene derivatives, [V(775-L5)(r77-C7H7)] [L^ = cyclopentadienyl ligand, C5H4-R (R = H (1), Me (la), 'Bu (lb)) and CsMes (lc); indenyl (2) and 2-methylindenyl (2a)]. The molecular structure of 2a has been determined: the distances between vanadium and the center Z of the (nearly parallel) ring ligands are 193.0 pm 
  Reference    Z. Naturforsch. 54b, 899—903 (1999); received April 8 1999 
  Published    1999 
  Keywords    Sandwich Compounds, Cycloheptatrienyl Complexes, Vanadium, Crystal Structure 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-0899.pdf 
 Identifier    ZNB-1999-54b-0899 
 Volume    54