| | 1 | Author
| Ulrich Nagel, Christoph Roller | Requires cookie* | | | Title
| Enantioselective Catalysis, XVII [1], Enantioselective Catalytic Hydrogenation of Unfunctionalized Ketones  | | | | Abstract
| Three diastereomeric rhodium bisphosphane complexes have been applied to asymmetric hydrogenation of unfunctionalized, non-chelating aliphatic and aromatic ketones. The ee values o f the catalysis products differ considerably for the diastereomerical catalysts. 70% ee were obtained in hydrogenating butyrophenone, and 83.7% ee for pinacoline. The results depend strongly on the solvent used. | | | |
Reference
| Z. Naturforsch. 53b, 267—270 (1998); received January 15 1998 | | | |
Published
| 1998 | | | |
Keywords
| Enantioselective Hydrogenation, Unfunctionalized Ketones, Rhodium, Salt Effect, Solvent Effect | | | |
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| default:Reihe_B/53/ZNB-1998-53b-0267.pdf | | | | Identifier
| ZNB-1998-53b-0267 | | | | Volume
| 53 | |
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